锂离子电池SnS_2负极材料的研究.pdfVIP

第38 卷 第2 期 河 北 工 业 大 学 学 报 2009 年4 月 Vol.38 No.2 JOURNAL OF HEBEI UNIVERSITY OF TECHNOLOGY April 2009 文章编号：1007-2373 (2009) 02-0074-04 锂离子电池 负极材料的研究 张海芳，张 颖，韩恩山，汪大云 （河北工业大学 化工学院，天津 300 130 ） 摘要 以SnCl 和硫代乙酰胺为原料，采用水热法制备了纳米SnS ，并对其结构和电化学性能进行了研究．研究 4 2 表明：电流密度对SnS2 电极的电化学性能有很大的影响．0.1 C 放电，首次充电容量可以达到448.7 mAh/g，但 20 次循环后容量衰减很大；而0.5 C 放电，首次充电容量虽然不高，但是30 次循环后容量可以保持在一个较高 的水平． 关 键 词 纳米SnS ；水热法；电流密度；电化学性能；锂离子电池 2 中图分类号 TM9 12 文献标识码 A Study on SnS as Anode Material for Lithium Ion Batteries 2 ZHANG Hai-fang ，ZHANG Ying ，HAN En-shan ，WANG Da-yun ( School of Chemical Engineering and Technology, Hebei University of Technology, Tianj in 300130, China ) Abstract Nanosized SnS powders were successfully prepared by hydrothermal reaction using SnCl and thioacetamide 2 4 as starting materials, and structure as well as the electrochemical properties were studied . Studies suggest that current density for discharge and charge has a effect on the electrochenical properties. 448.7 mAh /g was obtained after initial charge and capacity fading was large after 20 cycles at 0.1C rate, however initial charge capaciy was not more than the capaciy at 0.5C rate, a high capaci