电纺具有发光性能的共轭聚合物%2fPMMA纳米纤维.pdfVIP

电纺具有发光性能的共轭聚合物/PMMA 纳米纤维* ** 谭松庭 ，邹应萍，袁柱良，于宗强 （湘潭大学高分子材料研究所，湖南湘潭，411105 ） 探索具有一维纳米结构的新材料和新的制备方法是近几年的一个研究热 点。电纺（electrospinning ）技术可以方便地制备直径从几微米到几纳米的具有 高长径比纤维。借助电纺技术制备具有发光性能的纳米纤维可能在纳米材料和纳 米器件领域具有应用前景[1-3]。 本研究合成了发光共轭聚合物PPV 衍生物PMO-PPV ，并将其与甲基丙烯酸甲酯 (PMMA)共混，采用电纺技术制备了共轭聚合物/PMMA 发光纳米纤维，并考察 了其发光性能。研究结果表明, 具有直径范围从70 nm 至200 nm 的电纺纤维可 以发出明亮的黄绿光。与纯共轭聚合物PMO-PPV 膜相比, 电纺纤维的发光波长 与PMO-PPV 膜一致，但发光强度明显大于膜的发光。表明PMMA 作为电纺聚 合物的基体，不仅改善了共轭聚合物的可纺性，而且有利于共轭聚合物的光致发 光。其原因主要是PMMA 的引入，减少了共轭聚合物的浓度淬灭。 Electrospun conjugated polymer - PMMA Nanofibers with Photoluminescence Properties Songting Tan, Yingping Zou, Zhuliang Yuan, Zongqiang Yu Institute of Polymer Materials, Xiangtan University, Xiangtan 411105, P R China In this study, we present a facile approach for fabricating conjugated polymer nanofibers with strong photoluminescence properties via a electrospinning technique by blending conjugated polymer with poly(methyl methacrylate) (PMMA). One of PPV derivatives, poly(2-methoxy-5-octoxy)- 1, 4-phenylene vinylene) -alt-1, 4-(phenylene vinylene) (PMO-PPV), was employed as photoluminescence materials. PMO-PPV was synthesized according to the procedure as described in the Reference [4] and its average molecular weight is in the range of 7000-10000 (Mw). PMO-PPV is highly soluble in common organic solvents such as chloroform and can form a stable solution with PMMA. The electrospun fibers with diameters ranging from 70 nm to 200 nm were achieved (Figure 1) by electrospinning a 20 wt% PMO-PPV/ PMMA blending in CHCl3 solution. The photoluminescence (PL) spectrum of the electrospun fibers were shown in Figure 2. As compared to the PL spectra of the net