PMNNTCoFe2O4复合材料的结构和磁电性能.pdfVIP

34 10 Vol.34 No.10 2 0 0 6 1 0 JOURNAL OF THE CHINESE CERAMIC SOCIETY October2006 PMNNT/CoFe O 2 4 100084 Pb[ Mg Nb Ni Nb Ti ]O PMNNT CoFe O 1200 1/3 2/3 0.536 1/3 2/3 0.128 0.336 3 2 4 PMNNT CoFe O 2 4 TB332 A 0454–5648 2006 10–1213–07 STRUCTURE AND MAGNETIC ELECTRIC PROPERTIES OF PMNNT/CoFe2O4 COMPOSITES ZHOU Jianping HE Hongcai SHI Zhan ZHANG Xiaowen PAN Jingsong NAN Cewen State Key Laboratory of Advance Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China Abstract: Magnetoelectric particulate composites of Pb[ Mg Nb Ni Nb Ti ]O PMNNT and CoFe O with 1/3 2/3 0.536 1/3 2/3 0.128 0.336 3 2 4 various compositions were prepared by conventional ceramic calcining. PMNNT and CoFe2O4 structures were kept and no new phases were formed in the samples after sintering at 1 200 . However, element diffusion occurred between PMNNT and CoFe O 2 4 phases. The composites exhibit good ferroelectric and magnetic properties, such as higher dielectric constant, high piezoelectric con- stant, high saturation magnetization, low coercivity and high magnetostriction. The composites also demonstrated a magnetoelectric effect. Key words: composite; dielectric properties; ferroelectric properties; magnetic properties; magnetoelectric effect CoFe O [8–13]NiFe O [8,14–17] Tb Dy Fe [18–20] 2 4 2 4 0.28 0.72 2 [1] 3 1 Cr [2–3] 2O3 BiFeO3[4] BaMnF4[5] 0–3 [13–14] HoMnO3[6] 2 2–2 [8–9,15–19] 3 1–3 [10–12,20] [7] [21] [14] [22] – [8,15–16] [9–13] Pb Zr,Ti O3[8–9]BaTiO3[10–11] 2006–02–27 2006–05–24 Received data: 2006–02–27. Approved data : 2006–05–24. First author: ZHOU Jianping 1970— , male, doctor. E-mail: zhoujp@ 1970 Correspondent author: NAN Cewen 1962— , male, professor. 1962 E-mail: cwnan@ · 1214 · 2006 ?E Q αE 1 ?H CD?H Q DHF–2 [14] Pb C D TiMg ?H SP1641B Helmholtz 1 Hz3 MHz Pb[ Mg Nb Ni Nb Ti ]O Helmholtz 20 V 1/3 2/3 0.536 1/3 2/3 0.128 0.33