促释磷肥的结构特征及其有效性机理研究.pdfVIP

中国农业科学 2013,46(4):769-779 Scientia Agricultura Sinica doi: 10.3864/j.issn.0578-1752.2013.04.011 促释磷肥的结构特征及其有效性机理研究 黄 雷，毛小云，王 君，邓冰露，王冠豪，廖宗文 （华南农业大学资源环境学院，广州510642 ） 摘要：【目的】揭示促释磷肥结构特征与磷素有效性的内在联系，探讨促释磷肥的有效性量化测定方法。【方 法】采用连续浸提和乙酸-乙酸钠测活性磷法，通过再活化手段及光谱学技术从持续活化能力及理化结构特征方面 揭示促释磷肥的有效性机理。【结果】木质素磺酸钠处理能显著提高磷矿粉的水溶性磷和活性磷含量，4 种促释磷 肥的8 次累积水溶性磷含量分别是对应磷矿粉的14.0、5.6、8.8 和5.1 倍；且乙酸-乙酸钠测得的活性磷与未处 理磷矿粉相比，提高了9.8%—93.1%。红外光谱和X-衍射分析结果表明，木质素磺酸钠对磷矿粉磷素的促释作用 2- 具有持续性，能有效改变磷矿粉本身的化学成键结构，促使难溶的或枸溶Ca-P 键转化为活性高的H PO ，降低磷 2 4 灰石结晶程度，提高其有效性。 【结论】促释处理能持续促进难溶性或枸溶性磷向活性磷转化，采用连续浸提和 乙酸-乙酸钠测活性磷法能够对促释效果进行评价。 关键词：促释；磷矿粉；连续浸提；乙酸-乙酸钠法；活性磷 Research on the Structural Characteristics of Promoted-Release Phosphate Rocks and Its Phosphorus Bioavailability Mechanism HUANG Lei, MAO Xiao-yun, WANG Jun, DENG Bin-lu, WANG Guan-hao, LIAO Zong-wen (The College of Natural Resources and Environment of South China Agricultural University, Guangzhou 510642) Abstract : 【Objective 】The objective of the study is to disclose the structural characteristics and their internal relation with phosphorus validity in the promoted-release phosphate rocks (PRPr), and discuss the method for quantitative determination of active phosphorus. 【Method 】Continuous water extraction (CWE) and digestion with acetic acid and sodium acetic mixture (ASA) were involved, and the re-activated experiments and spectroscopic techniques were carried out to explore the phosphorus validity mechanism of PRPr from promoted-release persistence and molecular structu