Statistical Approach to Identify Environmental Factors in Controlling Heavy Metal Concentrations in Sediment.pdfVIP

Statistical Approach to Identify Environmental Factors in Controlling Heavy Metal Concentrations in Sediment.pdf

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Statistical Approach to Identify Environmental Factors in Controlling Heavy Metal Concentrations in Sediment.pdf

JournalofEnvironmentalScienceandEngineeringA1(2012)1025-1035 FormerlypartofJournalofEnvironmentalScienceandEngineering,ISSN 1934-8932 … N 塌 StatisticalApproachtoIdenti Environmen inControllingHeavyMetalConcentrationsinSediment HassanAlshemmari一,EqbalA1.Enezi,LulwaAliandAli.AI.Dousari EnvironmentalScienceDepartment,KuwaitInstitutefo,ScientfiicResearch,KuwaitSafat13109,Kuwait 2.SchoolofCivilEngineeringandGeosciences,TheUniversityofNewcastleUponTyne,NewcastleUponryneNE17RU,UK Received:April25,2012 /Accepted:August6,2012 /Published:August20,2012 Abstract:Surfacesedimentsampleswerecollected rfom 35locationsin SulaibikhatBay Kuwait . Co,Cr,Cu,Ni.Pb andZn concentrationsweredetermined.Grainsizes,TOC(totalorganiccarbon).carbonate.mineralogicalandenvironmentaldatawerealso determined.Multiplelinearregressionisappliedtothedatafrom thesedimentsequentialextractionstoassesstherelativeimpo~ance ofmineralogicalandsedimentologicalfactorsincontrollingheavymeta1concentrationsinindividualchemicalrfactions(exchangeable. reducible,oxidizable,residua1)underdifferentenvironmenta1conditions.TheanalysisshowsthatgrainsizeT0C,calciumcarbonate andmineralsclearlyinfluenceheavymetalconcentrations.Fortheexchangeablerfaction.clay.grainsizeandthemineralpyritearethe mainfactors,whereasforthereduciblerfaction,T0C isthemainfactorinfluencingconcentrationsofZn Pb,Ni,CuandCr.Forthe , oxidizablerfaction,modellingshowsthatTOC isthemainfactorinfluencingZn N iCu.CrandCoconcentrations.Theresidual , fractionconcentrationsofZn,Ni,CrandCowerebestpredictedbytheabundanceofsand

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