Structural and Electrical Characterization of PbS Ni Nanocrystallites Synthesized by Chemical Bath Deposition.pdfVIP

Structural and Electrical Characterization of PbS Ni Nanocrystallites Synthesized by Chemical Bath Deposition.pdf

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Structural and Electrical Characterization of PbS Ni Nanocrystallites Synthesized by Chemical Bath Deposition.pdf

JournalofMaterialsScienceandEngineeringA3(2)(2013)92-103 … N 《 StructuralandElectricalCharacterizatiOnofPbS:Ni NanocrystallitesSynthesizedbyChemicalBath Deposition MelissaCh吞VezPortillo,Rene.Guti6rrezP6rez2Mois6sAraizaGarcia3M arcialZamoraTototzintle,Andr6s , , CamachoYfifiez,AlbinoMorenoRodriguez,GenaroCarmonaGuti~rrez andOscarPortilloM oreno 1.FacultaddeCienciasQu[micas.BenemdritaUniversidadAut6nomadePuebla.C.UPuebla.72001Pud..Mdxico 2.Lab.SintesisdeComplejos,FacultaddeCienciasQuimicas,BenemitaUniversidadAut6nomadePuebla,Puebla,72001Pud, M $xico 3.ITESM CampusPuebla,ViaAtlixcayotf2301ColoniaReserva]rerritorialAtlixcayolt,CP.72453,Mdxico Received:February 16,2012/Accepted:March20,2012/Published:February10,2013 Abstraet:ThegrowthofnanocrystallinePbSfilmsbychemicalbathdeposition(CBD)ontoglassatadepositiontemperatureof204- 2。C isreposed.DifferentdopinglevelswcrcobtainedbychangingthevolumeofthereagentsolutionVN[i2+1intothePbSgrowing so1.ionwereadded.X-raydiffraction(XRD),TransmssionMicroscopyElectronic(TEM),Ramna spectroscopy (RS),drak conductivity(DC、measurementswasca~iedouttocharacterizethePbSfilms.XRDspectradisplayedpeaksattheangulrapositions: 20=(26.00,30.07,43.10,51.00,53.48),indicatinggrowthonthezincblendeface.Thegrainsize(GS)determinedbyx-raysdiffraction oftheundopedsamples,wasfoundtobe-36nm,whereaswiththedopedsampleisfoundtobeintherange-32-5nm,ascalculatedby employingScherer’sformula.ByTEM .thedoped-PbSmaterialswerefoundcrystallinefilmsintherange3.5-5am.RSexhibitedband centredat~l35cm~displayingonlyaPbSZBstructure.excludingthepresenceofnayothermateria1.Thethermalenergyforthefilms wasdeterminedfrom theslopeofDCna dtheenergywasestimatedtobeO.15to0.5eV.Finally.Gibbsfreeenergycalculationforthe VFNi2+1dopingP·bSprocesswasalsoestablished. Key

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