LiFePO4和LiFePO4与C复合物的合成分解.ppt

Synthesis of LiFePO4 and LiFePO4/C The 9th Group:孙毅 张鑫狄 陈祥洲 何炜 凌意瀚 Outline Fundamental concepts Synthesis and properties 1、solid-state reaction 2、mechanical activation 3、a new method—gas-phase diffused permeation (DP) method References BYD—“iron battery”? Two possible models for lithium extraction/reinsertion into LiFePO4 Advantage and disadvantage Solid-state reaction Mechanical activation Gas-phase diffused permeation (DP) method References 1、Characterization of LiFePO4 as the cathode material for rechargeable lithium batteries J. Power Sources 2001 2、A modified mechanical activation synthesis for carbon-coated LiFePO4 cathode in lithium batteries Material Letter 2007 3、Synthesis and electrochemical performance of LiFePO4/C prepared by a new method Solid State Communications 2008 4、The source of first-cycle capacity loss in LiFePO4. J Power Sources, 2001, 5、Lithium extraction / insertion in LiFePO4: an X-ray diffraction and Mossbauer spectroscopy study Solid State Ionics 2000 6、Synthesis and electrochemical properties of olivine LiFePO4 as a cathode material prepared by mechanical alloying J. Power Sources 2004 * * Lithium-ion battery The structure of LiFePO4 Theoretical capacity:170mAh/g Flat discharge voltage, High thermal and chemical stability, Low material cost Low toxicity and improved safety. Advantage: Disadvantage: Slow lithium ion diffusion Poor electronic conductivity Improve coat the active particles with conductive carbon LiOH·H2O NH4H2PO4 FeC2O2·H2O Mix together and heal 350℃,5h press into pellets thermal treatment powder 70℃,14h 675℃,725℃,800℃,24h J. Power Sources 2001 High temperature preparation cause particle growth and provides a smooth surface. Material with a high capacity had a large specific area. The specific surface areas of the materials prepared at 675,725,800℃ were 3.6,1.2 and 0.6m2/g,respectively. LiFeO4:acetylene black:PTFE=70:25:5 Li2CO3 NH4H2PO4 FeC2