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General Chemistry Examination (1) 首 页 I. There are 20 Questions. Circle your answer clearly; otherwise no credit will be given. Circle only one answer. If you circle two or more, you will receive no credit. 1．A 0.40-g sample of a polypeptide dissolved in 1.0L of an aqueous solution at 27(C has an osmotic pressure of 499Pa. What is the molar mass of the polypeptide? (A)2.0g(mol-1 (B)2.0(10-3 g(mol-1 (C)2.0(103 g(mol-1 (D)2.0(1023 g(mol-1 2．Raw milk sours in about 4 h at 28(C but in about 48 h in a refrigerator at 5(C. What is the activation energy for the souring of milk? (A)75kJ(mol-1 (B)75J(mol-1 (C)150kJ(mol-1 (D)150J(mol-1 3. What is the molar mass of a substance which, when 0.1g is dissolved in 10g of water, lower the freezing temperature to –0.155(C ？(Given Kf(water)= 1.86) (A)120 g(mol-1 (B)60 g(mol-1 (C)180 g(mol-1 (D)90 g(mol-1 4．Which of following solutions can not be used as buffer solution? (A)50mL 0.1mol(L-1 KH2PO4 solution + 50mL 0.1 mol(L-1 Na2HPO4 solution (B)50mL 0.1 mol(L-1 HAc solution + 50mL 0.1 mol(L-1 NaOH solution (C)50mL 0.1 mol(L-1 NH3 solution + 50mL 0.1 mol(L-1 NH4Cl solution (D)50mL 0.1 mol(L-1 Na2CO3 solution + 50mL 0.1 mol(L-1 NaHCO3 solution 5．In a neuron ( a nerve cell), the concentration of K+ ions inside the cell is about 20 to 30 times greater than that outside. What potential difference between the inside and the outside of the cell would you expect to measure if the difference is due only to the imbalance of potassium ions? (A)8V to 9V (B)+0.16V to +0.18V (C)+0.04V to +0.045V (D) +0.08V to +0.09V 6. Which nomenclature is incorrect? (A)[Fe(en)3]Cl3 ，三氯化三(乙二胺)合铁(Ⅲ) (B)[Co(NH3)5(H2O)]Cl3，氯化一水·五氨合钴(Ⅲ) (C) [Pt(NH3)4(NO2)Cl]CO3，碳酸一氯·硝基·四氨合铂(Ⅳ) (D)[Ni(CO)4]，四羰基合镍(0) 7. Novocaine, which is used by dentists as a local anesthetic, is a weak base with pKb = 5.05. Blood has a pH of 7.40. What is the ratio of concentrations novocaine to its conjugate acid in the bloodstream? (A)2.8 (B)2.8(10-