ywzhcs2.doc

General Chemistry Examination (2) 首 页 I. There are 15 Questions. Circle your answer clearly; otherwise no credit will be given. Circle only one answer. If you circle two or more, you will receive no credit. 1. A well is sunk in a bed of rock containing fluorspar (CaF2). Given that KSP (CaF2) = 4.0 x 10-11 at 298 K, and assuming that the water in the well is saturated with CaF2, and that the fluorspar is the only source of Ca2+ and F- ions, then the fluoride ion content of the water (in mol(L-1 at 298 K) is: (A) 1.3(10-5. (B) 2.2(10-4 (C) 4.3(10-4 (D)6.3(10-6 (E) 6.8 (10-4 2. Consider the reaction 2A → 4B＋C. What is the order of this reaction from the following straight line plot ? (A) half-order reaction . (B) second-order reaction ; (C) zero-order reaction ; (D) first-order reaction ; 3. For a certain first order reaction, the time required for half of an initial amount to decompose is 2 minutes. If the initial concentration of A is 0.8 mol(L-1, the time required to reduce the concentration of A to 0.2mol(L-1 is: (A)4.0min ; (B)1.0 min ; (C)8.0 min ; (D)2.5 min . 4. Which of the reactions below can NOT be forward？ (A) [MgY]2－ ＋Ca2+ ＝ [CaY]2+＋Mg2+ (B) [Cu(NH3)4]2+ ＋2en ＝ [Cu(en)2]2+＋4NH3 (C)[Fe(C2O4)3]3－＋6H+ ＝ Fe2+＋3H2C2O4 (D)[Fe(H2O)6]2+ ＋Y4－ ＝ [FeY]2－＋6H2O 5. A double bond between two carbon atoms is formed when: (A) one electron is shared (B) two electrons are shared (C) four electrons are shared (D)two electrons are transferred 6. The Lambert-Beer’s Law can NOT be represented by (A) -lgIt/I0 = Kbc (B) lgIt/I0 = εbc (C) lg1/T = εbc (D) A = Kbc 7. Commercial chemical suppliers sell perchloric acid (HClO4) as a 70.0% solution (by mass) in water. If the density of this reagent is 1.664 g(mL-1, what is the molar concentration of HClO4 in the solution? (A) 6.97 mol(L-1 (B) 16.6 mol(L-1 (C) 4.97 mol(L-1 (D) 23.2 mol(L-1 (E) 11.6 mol(L-1 8. The ion H3O+ is an a