ocean acidificationand alkalinity titration lesson plan（海洋acidificationand碱性滴定教案）.docVIP

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ocean acidificationand alkalinity titration lesson plan（海洋acidificationand碱性滴定教案）.doc

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This lesson was developed by Hilary Palevsky and Kevin Tempest from the University of Washington and by Lisa Neshyba and Kim Kaufman from Sammamish High School for use in AP Chemistry classes. The titration lab described in the second half of this lesson plan requires a standard titration setup with a calibrated buret and an acid of known concentration, as well as a seawater sample to titrate (you can collect water from Puget Sound for this too). The data collected from the titration can be entered into and analyzed with using the accompanying Alkalinity Titration Workbook in Excel. If you have questions about this material or want to share your experience using it, please contact palevsky@uw.edu. Ocean Acidification and Alkalinity Titration Lesson Plan Lesson Overview In this 90-minute lab, we will be discussing ocean acidification and alkalinity. We will measure the alkalinity of seawater by acid titration. Ocean Acidification is the process of the ocean pH decreasing (acidity increasing) through the input of dissolved CO2, which reacts with water to become carbonic acid (H2CO3). Ocean acidification impacts the distribution of inorganic carbon species (CO2, H2CO3, HCO3-, CO32-) by changing the pH of seawater. Alkalinity is a measure of the buffering capacity of seawater, or the total amount of H+ that can be absorbed by the solution (alternate definitions: excess of bases over acids; or difference in number of non-proton exchanging cations and anions in solution). To measure alkalinity, seawater is titrated with acid to a specified endpoint (pH=4.5) where essentially all of the proton acceptors have reacted. Why measure alkalinity? By measuring the alkalinity along with one other seawater property (fCO2, pH, or total dissolved inorganic carbon (DIC)), the total distribution of the species of the carbonate system (CO2/H2CO3, HCO3-, CO32-) can be precisely constrained. Why do we care about the carbonate system? Knowing the carbonate system is important for sever