fabricationofcalciayttriacompositesanditsproperties.docVIP

Material Sciences 材料科学, 2017, 7(1), 124-133 Published Online January 2017 in Hans. /journal/ms /10.12677/ms.2017.71016 Fabrication of Calcia/Yttria Composites and Its Properties Chengwan Cui, Dexin Zhang, Danbin Jia, Wenbin Dai*, Jingkun Yu School of Metallurgy, Northeastern University, Shenyang Liaoning Received: Jan. 6th, 2017; accepted: Jan. 19th, 2017; published: Jan. 22nd, 2017 Copyright ? 2017 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ s Abstract The main purpose of this paper is to investigate the differences in the microstructure and proper- ties of the composites resulting from the content of calcium oxide addition and sintering system. The results showed that the sintering condition of yttrium oxide was promoted with calcium oxide addition. At the same time, calcium oxide also improves the densification condition at low tem- perature. It is further found that 1 mol% calcium oxide can significantly promote the sintering condition. However, the sintering process will not be improved with the increase of calcium oxide content or sintering time. In this process, calcium oxide dissolved in yttrium oxide and calcium oxide precipitates on the grain boundary when the calcium oxide addition is over 6.5 mol%. Keywords Y2O3, CaO, Preparation, Property 氧化钙/氧化钇复合材料制备与性能 崔成万，张德新，贾丹彬，戴文斌*，于景坤 东北大学冶金学院，辽宁 沈阳 *通讯作者。 文章引用: 崔成万, 张德新, 贾丹彬, 戴文斌, 于景坤. 氧化钙/氧化钇复合材料制备与性能[J]. 材料科学, 2017, 7(1): 124-133. /10.12677/ms.2017.71016崔成万 等 摘 要 本文主要研究添加氧化钙至氧化钇基体中制备复合陶瓷，考察不同含量的氧化钙以及烧结制度对复合材 料的显微结构及性能的影响。结果表明，通过添加氧化钙，可以促进氧化钇的烧结，并且在较低的温度 下实现烧结体的致密化。氧化钙添加量为1 mol%即可显著促进烧结，但继续增加氧化钙含量或延长烧 结时间不会进一步促进烧结，试样中氧化钙固溶于氧化钇中，添加量超过6.5 mol%时，有氧化钙在晶界 处析出。 关键词 氧化钇，氧化钙，制备，性能 1. 引言 钇是人类发现的第一个稀土元素，其位于元素周期表ⅢB 族，原子量为 88.9。在自然界中钇与其他 重稀土元素总是共生在一起。我国不但拥有储量居世界第一的内蒙占白云鄂博轻稀土矿山，还拥有南岭地 区我国特有的重稀土资源。我国氧化钇工业储量达 22 万吨，占世界总储量 51 万吨的 43%，也居世界首位。 氧化钇是固体电解质和精密陶瓷的优良稳定剂，其为白色略带黄色粉末。密度为 5.01 g/cm3，不溶于 水和碱，溶于酸。熔点为 2410℃，介电常数为 12