新型耐高温复合纳滤膜的制备及性能.pdf

B101 新型耐高温复合纳滤膜的制备及性能 张守海 蹇锡高 杨大令 大连理工大学化工学院高分子材料系，辽宁 大连 116012） 要 以磺化含二氮杂萘酮结构聚芳醚砜酮为涂覆层材料，含二氮杂萘酮结构聚芳醚砜酮超滤膜为底膜， 制备了磺化聚芳醚砜酮复合纳滤膜，考察了浸涂稀溶液的溶剂和添加剂对复合膜性能的影响。复合膜对无机盐 的脱盐率顺序为：Na SO NaClMgSO MgCl 。将复合膜浸泡于氢氧化钠水溶液(PH= 13)中，浸泡 2 4 4 2 于5%的盐酸水溶液中，或浸泡于100mg L-1 次氯酸钠水溶液中，复合膜对Na SO 的脱盐率和 2 4 水通量均变化不大。复合膜于沸水中煮2.5 小时，膜对Na SO 的脱盐率和水通量均未下降。表 复合膜具 2 4 有耐碱、耐酸、耐氯和耐热等性能。 关键词 磺化聚芳醚砜酮 纳滤 复合膜 制备 性能 中图分类号 TQ 028.8 文献标识码 A 文章编号 PREPARATION AND PERFORNMANCE OF NOVEL COMPOSITE NANOFILTRATION MEMBRANES ZHANG Shouhai, JIAN Xigao and YANG Daling (Depa rtment of Poly mer Science Material, Dalian University of Technology, Dalian 116012,liaonin, China) Abstract Composite nanofiltration membranes with sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK) as top layer coated on poly(phthalazinone ether sulfone ketone) (PPESK) ultrafiltration (UF) membrane were prepared. The effects of different preparation conditions such as solvents and additives in SPPESK coating solution on the composite membrane performance were studied. The salt rej ection increased in the order MgCl MgSO NaCl Na SO for composite 2 4 2 4 membrane thus prepared. At room temperature and 0.25MPa SPPESK composite membranes rej ections -1 -2 -1 and fluxes for 1000mg L Na SO feed solution were 64-92%and 11-29 L m h respectively. SPPESK 2 4