大气污染物垂直廓线扫描差分吸收光谱方法研究.pdfVIP

第 29 卷第 2 期 2009 年 2 文章编号， 0253啕2239 (2009) 02-0297-06 光学学报 ACT A OPTICA SINICA Vol. 29 , No.2 2009 大气污染物垂直廓线扫描差分吸收光诸方法研究 朱族舞谢品华要科刘世胜秦敏李素文司福棋刘文清 {中阔科学院合肥物质科学研究院.环境成学与技术鼓点实骑室，安徽合肥 230031) 摘要 经分光学吸收光;普法(I)OAS) 已经成为测屋大气痕f毒气体含量的常用方法，该方法灵敏度高，可同时监测多 种大气痕最气体 ω 提出 f应用!l:分吸收光谱方法监测大气痕锺气体垂直分布，结合放宽数量去角反射器的近地居高 塔，研制出扫描长光程羔分吸收光满(扫描 LP-DOAS)系统。应用此系统于 2007 年夏季对北京城市意要大气污染 物 N02 的委班分布进行了外场监测，准确获得了 N02 沿各光路的积分浓度，确定了系统在各光赂的检测限和系统 总的测量误差。基于垂直廓线模型.成功反演了 N02 的垂直廓线和垂直梯度。研究结果表明扫描 LP-DOAS 技术 监测城市大气近地层痕量气体垂;应分布的可行性。 关键诩 大气光学 s 拘捕长光程差分吸收光谱系统;羹R廓线服恻.~氧化氮 中图分类号 。433.4 文献标i只码 A doi: 10.37881 AO 0297 Study on Scanning Differential Optical Absorption Spectroscopy for Monitoring Vertical Profiles of Atmospheric Pollutant Zhu Yanwu Xie Pinhua Dou Ke Liu Shisheng Qin Min Li Suwen Si Fuqi Liu Wenqing (俨Ke向叫6叼v川Lμαboraο旷州叫刚αωt川O叫叼ωvi衍r…m圳叫tω川α Chinese Ac佣αd础阶my 0/ Sci仿e阳7η品ω 8 , Hefei.A π hui 230031 , Chinα Abstract Differential optical absorption spectrωcopy (DOAS) has beωme a widely used method for the simulataneous detection of atmospheric trace gases with low detection limits. DOAS method is proposed for monitoring the vertical distribution of atmospheric trace gases . Based on DOAS technique and a high tower with angle-reflectors. the scanning long-path( LPl-OOAS system is developed . Field observations of vertical distribution of N02 was performed by using the scanning LP-DOAS sy日tem in the summer of 2007. The N也 concentrations along three light paths were accurately measured. and the detection limits along three light paths and the total systematic error were obtained. The vertical profiles and vertical gradient of N02 were successfully retrieved by using the vertical profiles model. The results indicate that the scanning LP-DOAS system can perform vertical observations of trace gases in the urban boundary layer. Key words atmospheric optics; scanning long-path differential optical absorption spectroscopy; monitoring of vertical profile. nitrogen dioxide 1 寻| 大气边界层是