Inductively coupled plasma mass spectrometry high purity rare earth impurities in neodymium oxide.docVIP

 PAGE \* MERGEFORMAT 16 Inductively coupled plasma mass spectrometry high purity rare earth impurities in neodymium oxide Study: Song Xuejie Liu Xinli Cheng Hang-Ting Chen too paragraph [Abstract] based on inductively coupled plasma quadrupole mass spectrometry determination of rare earth impurities in Nd2O3, focuses on the collision cell technology (CCT for the matrix Nd oxide and hydroxide ions to eliminate interference. Research shows that 10% O2 10% Ar 80% He as the collision reaction gases, maintain the reaction flow is 0.1 mL / min, and by tuning instrument parameters, access to 159Tb, 165Ho, 163Dy isotopes 175TbO, 179DyO and 181HoO strong oxide peaks appear, through the oxide ions were detected and achieve Tb, Dy, Ho quantitative analysis. Under the optimized conditions, the matrix oxides and hydroxides resulting from spectral interference can be reduced by 25 to 70 times. of the CCT mode with different internal standard elements in the matrix effect correction. The results show that, Re the best correction. The rest of La, Ce, Pr, Sm, Eu, Gd, Er, Tm, Yb, Lu and other elements determined by conventional model, in which Pr was determined by high resolution Nd front to eliminate the matrix interference peak. combined with interference factor correction, the established method for the purity of 99.999% Nd2O3, RSD less than 5%, the recoveries are satisfactory. [Key Words] high-purity substances, neodymium oxide, inductively coupled plasma mass spectrometry, collision cell, oxygen 1 Introduction High purity rare earth oxides have special physical and chemical properties, in the industrial sector and high technology has a wide application. With the advances in modern technology and new materials research continues to develop, on the various types of high purity rare earth oxides purity increasingly high demand, therefore, necessary to establish sensitive, accurate and fast method for quality evaluation and control. Currently, inductively coup