Antifungal and Spectral Studies of Cr(III) and Mn(II) Complexes Derived from -Thiodipropionic Acid Derivative英文文献资料.docVIP

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Antifungal and Spectral Studies of Cr(III) and Mn(II) Complexes Derived from -Thiodipropionic Acid Derivative英文文献资料.doc

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Antifungal and Spectral Studies of Cr(III) and Mn(II) Complexes Derived from -Thiodipropionic Acid Derivative英文文献资料

HindawiPublishingCorporation ResearchLettersinInorganicChemistry Volume2009,ArticleID945670,4pages doi:10.1155/2009/945670 ResearchLetter AntifungalandSpectralStudiesofCr(III)andMn(II)Complexes Derivedfrom3,3-ThiodipropionicAcidDerivative SulekhChandraandAmitKumarSharma DepartmentofChemistry,ZakirHusainCollege,UniversityofDelhi,J.L.NehruMarg,NewDelhi110002,India CorrespondenceshouldbeaddressedtoSulekhChandra,schandrachem@yahoo.co.in Received24April2009;Accepted7July2009 RecommendedbyGeorgiiNikonov TheCr(III)andMn(II)complexeswithaligandderivedfrom3,3 byelementalanalysis,molarconductancemeasurements,magneticsusceptibilitymeasurements,IR,UV,andEPRspectralstudies. Thecomplexesarefoundtohave[Cr(L)X]X2and[Mn(L)X]X,compositions,whereL=quinquedentateligandandX=NO3? -thiodipropionicacidhavebeensynthesizedandcharacterized , ? andOAc .Thecomplexespossessthesixcoordinatedoctahedralgeometrywithmonomericcompositions.Theevaluated ? Cl bondingparameters,Aisoandβ,accountforthecovalenttypemetal-ligandbonding.Thefungicidalactivityofthecompounds wasevaluatedinvitrobyemployingFoodPoisonTechnique. Copyright?2009S.ChandraandA.K.Sharma. This is an open access article distributed under the Creative Commons AttributionLicense,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkis properlycited. 1.Introduction synthesized according to the literature method [7]. The complexesweresynthesizedbyre?uxing1mmolofthemetal salt(nitrate,chloride,andacetate)with1mmolofligandin ThesynthesisofthecoordinationcompoundsoftheSchi?’s baseligandshavingN,S-donorbindingsiteshasattracteda considerableattentionbecauseoftheirpotentialbiological activities[1–3].Themainfeaturesofthesecompoundsare theirpreparativeaccessibility,diversity,structuralvariability and versatile coordinating properties. These compounds havealsobeenwidelyinvestigatedtoexaminethee?ectof metallation on the antipathogenic activities of such ligand systems. The studies of antipathogenic behavior of