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Bio Gas Oil Production from Waste Lard英文文献资料
HindawiPublishingCorporation
JournalofBiomedicineandBiotechnology
Volume2011,ArticleID384184,9pages
doi:10.1155/2011/384184
ResearchArticle
BioGasOilProductionfromWasteLard
Jen?oHancso′k,P′eterBaladincz,Tam′asKasza,Sa′ndorKov′acs,CsabaTo′th,andZolta′nVarga
MOLDepartmentofHydrocarbonandCoalProcessing,UniversityofPannonia,H-8201Veszpr′em,P.O.Box158,Hungary
CorrespondenceshouldbeaddressedtoJen?oHancso′k,hancsokj@almos.uni-pannon.hu
Received26October2010;Accepted10January2011
AcademicEditor:J.R.Botella
Copyright?2011Jen?oHancso′ketal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense,
whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited.
Besides the secondgenerations bio fuels, oneofthe mostpromisingproducts is the bio gas oil, which is a high iso-para?n
containingfuel,whichcouldbeproducedbythecatalytichydrogenationofdi?erenttriglycerides.Tobroadenthefeedstockofthe
biogasoilthecatalytichydrogenationofwastelardoversulphidedNiMo/Al2O3catalyst,andasthesecondstep,theisomerization
oftheproducednormalpara?nrichmixture(intermediateproduct)overPt/SAPO-11catalystwasinvestigated.Itwasfoundthat
boththehydrogenationandthedecarboxylation/decarbonylationoxygenremovingreactionstookplacebuttheirratiodepended
ontheprocessparameters(T =280–380
?
C,P = 20–80bar,LHSV = 0.75–3.0h?1andH2/lardratio:600Nm3/m3).Incaseof
?
C,P = 40–50bar,LHSV = 1.0h andH2/hydrocarbon
?1
theisomerizationatthefavourableprocessparameters(T =360–370
ratio:400Nm
3
/m
3
)mainlymono-branchingisopara?nswereobtained.TheobtainedproductsareexcellentDieselfuelblending
components,whicharepracticallyfreeofheteroatoms.
1.Introduction
corrosion; phosphor content → poisonous e?ect on the
three-waycatalyst,etc.)[1–3].
Nowadays the production and utilisation of agricultural
originfuelshavecometothefrontbecauseofenvironmental
protection,politicalandeconomicalreasons.Intheincrease
oftheutilisationofthesebio-fuelstheenergypolicyofthe
EuropeanUn
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