Buffer Standards for Physiological pH of the Buffer N-(2-Acetamido)-2-aminoethanesulfonic Acid from 5°C to 55°C英文文献资料.docVIP

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Buffer Standards for Physiological pH of the Buffer N-(2-Acetamido)-2-aminoethanesulfonic Acid from 5°C to 55°C英文文献资料.doc

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Buffer Standards for Physiological pH of the Buffer N-(2-Acetamido)-2-aminoethanesulfonic Acid from 5°C to 55°C英文文献资料

Open Journal of Physical Chemistry, 2011, 1, 118-123 doi:10.4236/ojpc.2011.13016 Published Online November 2011 (http://www.SciRP.org/journal/ojpc) Buffer Standards for Physiological pH of the Buffer N-(2-Acetamido)-2-aminoethanesulfonic Acid from 5?C to 55?C Lakshmi N. Roy, Rabindra N. Roy*, Zachary M. Downs, Blake M. Bodendorfer, Jaime A. Veliz, Jessica M. Stegner, Isaac B. Henson, Joshua T. Wollen Hoffman Department of Chemistry, Drury University, Springfield, USA E-mail: rroy@ Received August 23, 2011; revised September 27, 2011; accepted November 1, 2011 Abstract Electromotive force (emf) measurements of the Cell Pt(s), H2(g)|ACES(m1) + NaACES(m2) + NaCl (m3)| AgCl, Ag(s) have been carried out from 5 ?C to 55?C. The agreement of pH values between two calculated (extended Debye-Hückel and liquid junction correction) is very good. Two buffer solutions without the chlo- ride ion and seven buffer solutions with NaCl, at an ionic strength (I = 0.16 mol·kg ) similar to that of –1 physiological fluids, have been studied. The pH values for these buffer solutions have been evaluated in the temperature range of 5?C to 55?C using the extended Debye-Hückel equation of the Bates-Guggenheim con- vention. Values of the residual liquid junction potential ( δEj) between the ACES solutions and the saturated KCl calomel electrode solution have been estimated at 25?C and 37?C from the previously determined Ej val- ues using the flowing junction cell to determine the operational pH values at 25 ?C and 37?C. These ACES buffer solutions are recommended as secondary standard reference solutions for pH measurements in the –1 range of physiological application at I = 0.16 mol?kg . Keywords: Buffer, Emf, pH, Zwitterionic 1. Introduction The zwitterionic buffer compound ACES may form complexes with cations such as Mg and Ca . At a high +2 +2 The zwitterionic amino acid buffer solutions recom- mended by Good et al. [1,2] have been