Carbon Tubular Morphologies in Blast Furnace Coke英文文献资料.docVIP

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Carbon Tubular Morphologies in Blast Furnace Coke英文文献资料.doc

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Carbon Tubular Morphologies in Blast Furnace Coke英文文献资料

HindawiPublishingCorporation ResearchLettersinMaterialsScience Volume2008,ArticleID751630,4pages doi:10.1155/2008/751630 ResearchLetter CarbonTubularMorphologiesinBlastFurnaceCoke StanislavS.GornostayevandJoukoJ.Ha¨rkki LaboratoryofProcessMetallurgy,DepartmentofProcessandEnvironmentalEngineering,FacultyofTechnology, UniversityofOulu,P.O.Box4300,90014Oulu,Finland CorrespondenceshouldbeaddressedtoStanislavS.Gornostayev,ssg@cc.oulu.? Received5December2007;Accepted9April2008 RecommendedbyJe?reyGlass Thepaperreportsonthe?rstoccurrenceofmicroscalecarbontubularmorphologies(CMTs)inablastfurnace(BF)coke.The CMTswereprobablyformedasaresultoftheconversionofsoliddisorderedcarbonvialiquidphasemetalparticlesinvolvingagas phasecontainingasubstantialamountofN2andO2.ThepresenceofCMTsmayliebehindthegenerationofthesmallestfraction of?nesinBFexhaustdust.IftheamountofCMTspresentintheBFexhaustsgasesatanyparticularmetallurgicalsiteprovesto besubstantial,itcouldbecomeasubjectofenvironmentalconcern. Copyright?2008S.S.GornostayevandJ.J.H¨arkki. This is an open access article distributed under the Creative Commons AttributionLicense,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkis properlycited. 1. INTRODUCTION transformation.Avariantofthesolidstatemodelenvisages a“crystallization”ofnanotubesfromextendedassembliesof disordered carbon, while the liquid phase model assumes that nanotubes nucleate within globules of liquid carbon depositedontothecathode”[8].Itwasalsofoundthatheat treatmentscouldproducemicron-lengthSWCNTsatabout Carbon tubular morphologies are mostly known as nan- otubesandmicrotubes,implyinginternaldiametersinthe nanometerormicronrange,respectively.Carbonnanotubes, whichcanbesingle(SWNT)ormultiwalled(MWNT),have manypropertiesthatmakethempotentiallyusefulinawide variety of applications, including composites, electronics, pharmaceuticals, and optics. They are also known for the environmental and health risks attached to them [1–6].