SO2和H2o对Y掺杂Mn／TiO2选择性脱除NO的影响.pdfVIP

学兔兔 化 工 进 展 ·552· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第31卷第3期 SO2和H2o对Y掺杂Mn／TiO2选择性脱除NO的影响 刘晓肖，张舒乐，钟 秦，姚 瑶，李小海 (南京理工大学化工学院，江苏 南京210094) 摘 要：采用溶胶．凝胶法制备了Y掺杂的TiO2载体，负载硝酸锰构成了Y掺杂的Mn—Y／TiO2催化剂。考察了 焙烧温度、空速对其催化还原NO性能的影响，并对催化剂的抗SO2、H20毒化性能进行了考察。结果表明，催 化剂的最佳焙烧温度为500℃，催化剂的活性随空速的降低而升高，XRD分析Y掺杂抑制了锐钛矿晶相的转移， 有利于催化剂活性组分的分散，从而提高催化剂的活性。Mn．Y／TiO2的抗毒化性能优于Mn／TiO2，在反应温度180 ℃、空速14000 h 、氧含量为3％、NO浓度600 gL／L及NH ／NO为1的条件下，同时通入200 gL／L sO，和4％ H2O，NO转化率从非掺杂的Mn／TiO2的48．2％上升到57．6 0／oj Y掺杂提高了催化剂的抗毒化能力；FTIR分析表 明催化剂中毒是由于生成了铵的硫酸盐或者锰、钇的硫酸盐。 关键词：选择性还原NO；SO2和H20；锰／二氧化钛；Y掺杂 中图分类号：x 511 文献标志码：A 文章编号：1000—6613(2012)03—0552—06 Impact of 802 and 1-120 on catalytic performance of Y-doped Mn／TiO2 in the reduction 0f No LIUXiaoxiao，ZHANG Shule，ZHONG Qin，YAO Yao，LIXiaohai (School ofChemical Engineering，Nanjing University ofScience and Technology，Nanjing 210094，Jiangsu，China) Abstract：Y-doped TiO2 support was prepared by sol—gel method，followed by the impregnation of Mn oxides loading to form Mn—Y／TiO2 catalyst．The effects of calcination temperature and space velocity on the performance in the catalytic reduction of NO were studied．And the poisoned perform ance of anti-502，H20 was also investigated．The results showed that the optimal calcination temperature was 500℃，catalytic activity increased with the decrease of GHSV．XRD analysis indicates that Y doping could restrain the transfer from anatase phase to rutile，provide better dispersion of active components on catalyst surface，and therefore，i