Pd-catalyzed Synthesis of β-Biarylacryl Ferrocenes via Suzuki Cross-coupling 英文参考文献.docVIP

Molecules 2005, 10, 634-639 molecules ISSN 1420-3049 Pd-catalyzed Synthesis of β-Biarylacryl Ferrocenes via Suzuki Cross-coupling Qing-Bao Song 1,*, Ru-Xiang Lin 1, Zhen-Ping Yang 1 and Chen-Ze Qi 2 1 College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, 310014, Zhejiang Province, P. R. China. Tel. (+86) 571- Fax: (+86)-571- 2 The Institute of Applied Chemistry, Shaoxing College of Arts and Sciences, Shaoxing 312000, Zhejiang Province, P. R. China. Tel. (+86)-575-8341006, Fax: (+86)-575-8341006. * To whom correspondence should be addressed: E-mail: songqb@ Received: 2 April 2004 / Accepted: 30 August 2004 / Published: 14 July 2005 Abstract: Some novel β-biarylacryl ferrocene derivatives were synthesized via Pd-catalytic Suzuki cross-coupling reactions of β-(2-bromophenyl)acrylferrocene and arylboronic acids. The structures were determined with elemental analyses, IR spectra, and 1H-NMR spectra. Keywords: Pd-Catalyst; Biarenes; Ferrocenyl; Suzuki Cross- coupling Reaction. Introduction Over the last two decades, molecular-based second-order nonlinear optical (NLO) chromophores have attracted much interest because of their potential applications in emerging opto-electronic technologies [1-5]. These efforts have mainly focused on organic systems. More recently, organometallic molecules have been investigated as well [3-5]. In comparison to common organic molecules, they offer a large variety of novel structures. The possibility of high environmental stability and diversity of tunable electronic behaviors by virtue of the coordinated metal center might bring about NLO materials with unique characteristics such as magnetic and electro-chemical properties.  Molecules 2005, 10 635 In the present communication, we continue our previous research work [6] and wish to report the synthesis by Suzuki cross-coupling reaction [7]