螺螨酯在枸杞果实中消解动态探讨.docVIP

螺螨酯在枸杞果实中的消解动态研究 　　[摘要] 研究螺螨酯在枸杞鲜果、干果中的消解动态，为其在生产中的安全使用提供依据。参照《农药残留试验准则》进行螺螨酯消解动态试验，采用乙腈超声提取，高效液相色谱法进行残留检测分析。结果显示，24%螺螨酯悬浮剂在枸杞鲜果中的半衰期为69～112 d，在枸杞干果中的半衰期为85～104 d，属于易消解农药。参照欧盟制定的螺螨酯在枸杞中的最高残留限量（05 mgkg-1），建议推荐剂量（60 mgkg-1，54 ghm-2，4 000倍）1次施药的条件下，鲜用枸杞的安全间隔期为5 d以上，制干枸杞的安全间隔期为21 d以上 [关键词] 螺螨酯； 消解； 枸杞； 鲜果； 干果 Dissipation dynamics of spirodiclofen in wolfberry fruit LI Jianling1， LIU Sai1， XU Changqing1*， WEI He2， QIAO Haili1， GUO Kun1， XU Rong1， LIN Chen1， JIN Hongyu2， MA Shuangcheng2， CHEN Jun1* （1Institute of Medicinal Plant Development， Chinese Academy of Medical Science and Peking Union Medical College， Beijing 100193， China； 2Research and Inspection Center of Traditional Chinese Medicine and Ethnomedicine， National Institutes for Food and Drug Control， Beijing 100050， China） [Abstract] The dissipation of spirodiclofen in fresh fruit and dry fruit of wolfberry was detected in this study to provide a reference for its safe applicationAccording to Pesticide Residue Test Criteria of China， the openfield experiment was conducted in Zhongning courty of Ningxia province， and the dissipation of spirodiclofen was studied by acetonitrile extraction and HPLCMS/MS detectionThe results showed that the halflives of spirodiclofen in fresh wolfberry fruit and dry wolfberry fruit were 69112 days and 85104 days， respectivelySpirodiclofen belongs to the easily degradable pesticide typeAccording to the maximum residue limits （05 mgkg-1） of spirodiclofen of EU for wolfberry， after recommended dosage being sprayed for once， fresh wolfberry fruit was safe to eat after 5 days， and dry wolfberry fruit was safe to eat after 21 days [Key words] spirodiclofen； dissipation dynamics； wolfberry； fresh fruit； dry fruit doi：10.4268/cjcm 宁夏枸杞Lycium barbarum L为茄科Solanaceae多年生落叶灌木，果实（枸杞子）是我国大宗常用中药材。近年来，随着枸杞子需求量的增加，枸杞子价格不断上涨，枸杞种植面积随之快速增加，2013年全国种植面积达1 220 km2[1]。由于枸杞生长繁茂，营养生长与生殖生长同时进行，极易遭受害虫危害。生产中枸杞主要成灾害虫有7种[2]，枸杞瘿螨Aceria pallida Keifer是枸杞上的重要害虫，在我国枸杞主产区均有分布，由于