落叶松、杨木热处理材及压缩材热动态力学特性分析.pdfVIP

Vol. 36 No.4 第36 警第4 期 东北林业大学学报 2ω8 年 4 月 JOURNAL OF NORTHEAST FORESTRY UNIVERSITY Apr. 2∞8 落叶松、杨木热处理材及压缩材热动态力学特性分析1 ) 赵钟声刘一星沈隽 (东北林业大学，哈尔演，15∞40) 摘 要 对落叶松、杨木未压缩材和压缩材进行高温热处理，利用 DMA -242 型热分析仪对处理后的压缩材 和未压缩材进行热动态力学分析，并与其各自索材进行对比。通过分析模最、损耗角.iE..切等热动态力学参数的变 化规律，及热处理时间对压缩材和未压缩材中半纤维索、木质素等木材组成物质的影响，探讨其变化趋势和在变形 固定中的内在作用机理。结果表明，在玻璃态区域损耗棋爱和损耗角.iE..切随热处理时间延长而呈递减的趋势(尺 寸稳定性和压缩变形阁定效果增强) ，压缩材中热处理24h 者玻璃化转变起始温度大幅降低，即木质素大量低分 子化木材培变恢复丧失而形成压缩材变形固定。 关键词 木材热处竣;压缩材;热动态力学特性 分类号 578 1. 2 Tbennodynamic Property of Heat Treated and Compressed Larch and Poplar Wood/ZhωZhongsheng， Liu Yixi吨， Shen Jun( College of Material Science and Engíneeri吨， Northeast Forestry University , Harbin 15ω40 ， P. 民 China)11 Joumal of Northeast Forestry University. - 2∞8 ， 36(4). 由 17 叫 19 An e宜periment w.ωωnductedωstudy the thermodynamic properties of uncompressed 肌d compressed larch and pop- lar wo叫 after high temperature trea恤ent by DMA剖2 thermal analysis instrument. The properties of the heat treated wood wereωmpared with thωe of the control.四e changing tendency of the thermodynamic parameter四 and its intemal action mechanism in distortion and fixation were discussed by means of the changing regularity of loss tangent , 1佣s modwus and the ef{，酬。f the treating time on w.ωd component such 倒 hemi咄llwose and li伊in. Resw饱 show that 1仰自 tangent 8nd 10sB m叫ulus decrease with the extension of the treating time in glass state ar棚，且an时d the dimm町耐1阳ensiona必1 stability , the effects of ∞mpression ， distortion , and fixation are enforced. For the compressed wood heat-treated for 24 hours , the glass transition temperature declines dramatically , n8mely the fixation of the comp陀ssion is due to the c陀ep recovery 10暗自 f