长链烷基与聚醚共改性聚硅氧烷的合成及其在消泡剂中的应用.pdfVIP

第31卷第10期 印染 助 剂 Vol.31 No.10 2014年10月 TEXTILE AUXILIARIES Oct.2014 长链烷基与聚醚共改性聚硅氧烷的 合成及其在消泡剂中的应用 王安琪，郭 睿，杨 旭，郑淑华，窦尹辰 （陕西科技大学教育部轻化工助剂化学与技术重点实验室，陕西西安 710021） 摘 要：以含氢硅油、十二烯和烯丙基聚醚为原料,在氯铂酸催化剂作用下,合成了一种新型有机硅表面活性剂——长链烷 基、聚醚共改性聚硅氧烷(APMS).用自制硅膏、复合乳化剂(Span-80、Tween-80、OP-10)、烯丙基聚醚与APMS进行复配,得到了稳定的 APMS消泡剂乳液.优化的制备条件为:疏水白炭黑用量3%,复合乳化剂的HLB 值8.0,配比为n(Tween-80)∶n(Span-80)∶n(OP-10)=1∶5∶2, 用量5.5%. 关键词：含氢硅油; 长链烯烃; 烯丙基聚醚; 消泡剂; 复配; 应用 中图分类号: TQ423.95 文献标识码: A 文章编号: 1004-0439(2014)10-0020-04 Synthesis of long-chain alkyl and polyether modified polysiloxane and its application in defoamer WANG An⁃qi, GUO Rui, YANG Xu, ZHENG Shu⁃hua, DOU Yin⁃chen (KeyLaboratoryofAuxiliaryChemistry ＆TechnologyforChemicalIndustry,MinistryofEducation, ShaanxiUniversityofScience ＆Technology, Xi′an 710021, China) Abstract: A novel organic silicone surfactant, long-chain alkyl and polyether co-modified polysiloxane (APMS) was prepared from polydrosilicone oil, dodecene and allyl-polyether as materials in the presence of chloroplatinic-acid catalyst. Using self-made silicon paste, compounding emulsifier (Tween-80, Span-80, OP-10), allyl-polyether and APMS for distribution, the stable APMS defoamer emulsion was obtained. The op⁃ timal preparation conditions were: the amount of hydrophobic silica was 3 %, the HLB value of compounding emulsifier was 8.0, the mass fraction of the emulsion was 5.5%, and the molar ratio of Tween-80, Span-80 and OP-10 was 1∶5 ∶