环氧氯丙烷装置丙烯醇单元工艺优化.pdfVIP

de-heavy components column by means of ASPEN PLUS and analyzed the influence of the feed location,reflux ratio,operation pressure and withdrawal amount to the separating effect of the column.These provided important secundum for the operation and optimization of the column in the future.At the end,the innovative points are summarized and the future research direction is decided. Througn the implementation of the project, the production process of propenol unit was optimized, the age of catalyst was prolonged,the removal efficiency and maneuverability of the de-heavy components unit were improved,the level of long-cycle stable operation of the plant was raised,and much contribution was made to create benefits to our company. Keywords: epichlorohydrin ； propenol; catalyst deactivation; de-heavy components; process optimization 万方数据 目 录 前 言1 第一章 文献综述 1.1 环氧氯丙烷的性质及用途3 1.2 丙烯醇的性质及用途3 1.3 环氧氯丙烷的主要生产工艺4 1.3.1 丙烯高温氯化法4 1.3.2 醋酸丙烯酯法5 1.3.3 甘油法7 1.3.4 三种生产工艺的技术指标比较8 1.3.5 其它生产环氧氯丙烷的工艺9 1.4 环氧氯丙烷的生产概况10 1.4.1 国外环氧氯丙烷的生产概况10 1.4.2 国内环氧氯丙烷生产概况11 1.5 催化剂的分析表征方法12 1.5.1 催化剂宏观结构与性能表征13 1.5.2 催化剂微观结构与性能表征13 1.6 化工过程的稳态模拟和工具软件16 1.7 本课题研究内容17 第二章 Pd/SiO 催化剂失活原因分析及工艺优化 2 2.1 Pd/SiO 催化剂特性介绍18 2 2.1.1 Pd/SiO 催化剂组成18 2 2.1.2 Pd/SiO 催