活性自由基聚合,TEMPO.pptVIP

2.4 副反应 苯乙烯中的热引发： 说明双基终止的存在? 热引发对苯乙烯的聚合十分有利！ 双基终止的程度：严重影响速率，对分子量和分布影响很小！ 因自由基浓度:约为10-8M，大分子浓度为10-2M! * 2.4 副反应 烷氧胺的分解或提氢副反应： * 2.4 副反应 烷氧胺的分解或提氢副反应： These results help to explain the differences in the polymerization of styrenics and methacrylates under the same NMP conditions. Due to the extra β hydrogens on the methacrylates, there is a much greater amount of H transfer and therefore lack of control. This has been observed experimentally with significant amounts of “ene” terminated polymer chains detected by MALDI-MS and NMR and UV-vis studies. Acrylates : much greater amount of H transfer