原位反应法制备Al-Ti-B-RE晶粒细化剂及其细化效果.pdfVIP

铸 造 Dec．2007 · FOUNDRY V0I．56 N0．12 1324· 原位反应法制备Al—Ti—B—RE晶粒细化剂 及其细化效果 陈永禄 ，傅高升 ，陈文哲 (福建工程学院材料科学与工程系，福建福州350014；2．福建交通职业技术学院，福建福州350007) 摘要：以K TiF 、KBF 、A1．10RE~添加物，采用原位反应法制备了Al—Ti—B-RE中间合金，通过正交法优化出各合金元 素的合理配比，即5％Ti、1％B、0．5％RE，Ti元素的吸收率达92．4％。RE元素进)~TiA13相，阻碍其生长，TiA13相以小块 状为主，分布较均匀，增强细化效果。利用该细化剂对A356~合金进行细化处理，其晶粒尺寸仅为经A1-5Ti—B处理过 的晶粒的42-2％，枝晶间距明显缩小。 关键词：A1．Ti—B．RE合金；细化剂；晶粒细化；原位反应 中图分类号：TG111．4，TG146．2 文献标识码：A 文章编号：1001—4977(2007)12—1324—04 Preparation of AI--Ti--B--RE Grain Refiner by In--Situ Reaction Method and Its Refining Effect CHEN Yong-lu ，FU Gao-sheng ，CHEN Wen-zhe (1．College of Material and Engineering，Fujian University of Technology，Fuzhou 35001 4，Fujian， China；2．Fujian Communication Technology College，Fuzhou 350007，Fujian，China) Abstract：Take K2TiF 6，KBF4，A1．1 ORE alloy as supplements，the Al-T__B-RE intermediate alloy has been prepared by adopting in-situ reaction．The blending ratio of alloying elements is optimized by means of o~hogonal experiment，that is 5％Ti，1％B，O．5％RE，and the absorptivity of Ti can reach 92,4％．The RE elements enter the T_Al3 phase and hinder its growth．The T_Al3 phases in the all0v are mainly small bulk and distributed evenly。so the refining effect is enhanced．The grain size of A356 aluminum alloy refined by adding the Al。5Ti。B。0．5RE refiner is reduced to 42．2％of the grain refined by addinq the Al-5Ti-B refiner．and the dendrite spacing iS also reduced obviously． Key words：Al-T__B-RE alloy；refiner；grain refinement；in-situ reaction 晶粒细化是改善铝材质量，提高其强韧性的重要 1 试验条件与方法 途径。随着铝材的广泛应用，对铝锭、坯在后续深加 工工艺中的组织