含异氰脲酸酯结构聚醚多元醇的合成.pdfVIP

第30卷第6期 火 炸 药 学 报 2 0 0 7年1 2月 Chinese Journal of Explosives＆Propellants Synthesis of Poly(ether glyco1)s Containing Isocyanurate Segments CHANG Hai，FAN Xiao—dong，WANG Sheng—jie (Department of Applied Chemistry，School of Science，Northwestern Polytechnical University，Xi an 710072，China) Abstract：The cationic ring—opening polymerizations of epoxide based monomers were studied USing tris(2 hydrooxyethy1)isocyanurate(THEIC)as initiator and trifluoroboron plus ether complex system as catalyst．It was found that the ring opening polymerizations of epoxide based monomers with THEIC can be carried out in a heterogeneous medium smoothly．However，using THEIC initiator，the reaction rate for epichlorohydrin is faster than that of propylene oxide and 2-butoxyxirane，respectively．By simply adjusting the monomer feeding sequence， the block poly(ether glyco1)copolymers containing isocyanurate segments can be prepared successfully ． Key words： organic chemistry； poly (ether glyco1)s； tris(2 hydroxythy1) isocyanurate； ring opening polymerization；epoxide based monomers 中图分类号：TJ55；TQ223．3 文献标志码：A 文章编号：1007—7812(2007)06—0013 04 含异氰脲酸酯结构聚醚多元醇的合成 常 海，范晓东，王生杰 (iN北工业大学理学院应用化学系，陕西 西安 710072) 摘 要：以1，3，5-三羟乙基异氰脲酸酯(THEIC)为引发剂、三氟化硼乙醚络合物为催化剂，环氧化合物为环单体， 进行了阳离子开环聚合反应的研究。发现THEIC与环氧单体可在非均相体系中平稳地进行阳离子开环聚合反应。 在THEIC体系，就链引发而言，环氧氯丙烷的大于环氧丙烷、丁基醚环氧乙烷。调整环单体加料次序就可以获得嵌 段共聚醚多元醇。 关键词：有机化学；聚醚多元醇；三羟乙基异氰脲酸酯；开环聚合反应；环氧单体 on， Considering THEIC possessing the similar Introduction ch