十二烷基苯磺酸钠和链烷醇酰胺复配体系中组分含量的测定.pdfVIP

PTCA(PART B: CHEM. ANAL.) 001: 10. 11973/lhjy-t皿201512018 十二烧基苯磺酸纳和链皖醇酷肢复配体系中 组分含量的测定 石东坡，尹先清，郑延成，陈 武，付家新，任朝华 (长江大学油气资源与勘探技术教育部重点实验室，荆州 434023) 摘要:分别采用荧光光谱法和化学分析法测定复配溶液中的十二;比基苯磺酸纳(SDBS) 和链 坑醇耽脏的含量。在复配溶液中加入与 SDBS 等物质的量的卢环糊精，不仅能增强 SDBS 的荧光 强度，还能显著降低烧醇眈接对 SDBS 的干扰。采用荧光光谱法测定复配溶液中 SDBS 的含量，加 标回收率在 101%~102%之间。又在试样溶液中以硫酸作为催化剂，使其中的链坑醇眈胶水解， 反应时间为 10 h，随后采用化学分析法测定复配溶液中坑醇眈牍含量，加标回收率在 98. 2%~ 98.9%之间。 关键词: SDBS 与烧醇眈牍复配体系;荧光光谱法;化学分析法;~环糊精 中图分类号: 0657.3 文献标志码:A 文章编号: 1001-4020(201日12-1713-04 Determination of Components in the Complex System of Sodium Lauryl Benzenesulfate 缸ld Alkanolamide SHI Dong-po , YIN Xian-qi吨， ZHENG Yan-cheng , CHEN Wu , FU Jia古in ， REN Zhao-hua (Key Laboratory 0/ E :rploration Technologies for αl and Gas Resources , Yangtze University , Jingzhou 434023 , China) Abstract: Fluorospectrophotometry and chemical method were applied to the determination of sodium lauryl benzenesulfate (SDBS) and alkanolamide (AKNM) in the complex systems. An amount of 卢cyclodextrin with its molar concentration approximately equivalent to that of the SDBS in the sample solution molar of SDBS was added to enhance the fluorescence intensity of SDBS and to reduce significantly the interference of alkanolamide to SDBS. SDBS in the complex solution was determined by fluorospectrophotometry , giving values of recovery foun by standard addition method in the range of 101 % -102%. After the sample solution was hydrolyzed for 10 h with sulfuric acid added as catalyst , content of AKNM was determined by chemical method , giving values of recovery found by standard addition method in the range of 98. 2 %