BGO晶体生长固液边界层结构的微区研究.pdfVIP

第36卷 第6期 人 工 晶 体 学 报 Vo1．36 No．6 2007年l2月 JOURNAL OF SYNTHETIC CRYSTALS December，2007 BGO晶体生长固液边界层结构的微区研究 张 霞 ，万松明 ，殷绍唐 ，尤静林 ，陈 辉 ，赵思杰 ，张庆礼 (1．中国科学院安徽光学精密机械研究所，合肥230031；2．上海大学上海市钢铁冶金新技术开发应用重点实验室，上海200072) 摘要：研究了BGO晶体固／液边界层及其两侧晶体和熔体的高温拉曼光谱，分析了BGO晶体生长固／液边界层以及 边界层两侧晶体和熔体的结构特征。结果显示，桥氧键Bi—O-Ge和O—Bi．O在晶体和边界层中都存在，而在熔体中 消失。说明[GeO ]和[BiO ]结构基团在晶体及边界层中都存在，边界层中的结构已接近晶体结构；但在熔体中 [GeO ]结构基团和B 却是两种独立的存在，长程有序的晶体结构消失。并首次报道了BGO晶体固／液边界层的 厚度约为5O“m。 关键词：固／液边界层；高温拉曼光谱；BGO晶体；实时观测 中图分类号：078 文献标识码：A 文章编号：lO00-985X(2007)06—1245-04 Analysis on Raman Spectra of Growth Solid-liquid Boundary Layer of BGO Crystal ZHANG Xia ，WAN Song．ming ，YIN Shao．tang ，YOU Jing．1in ，CHEN Hui ， ZHAO Si-jie ，ZHANG Qing．1i (1．Anhui Institute of Optics and Fine Mechanics，Chinese Academy of Sciences，Hefei 230031，China；2．SharIg}Iai Enhanced Laboratory of Ferro—metallurgy，Shanghai University，Shahghai 200072，China) (Received 27 March 2007，accepted 16 ArIr／／2007) Abstract：The high·temperature Raman spectra of the growth solid—liquid boundary layer of BGO crystal were studied．The structure characters in boundary layer，melts and crystal were analyzed．The results show that there exits[GeO4]polyhedral structure and Bi ion independently in BGO melt．The bridge bonds Bi·O·Ge and O·Bi·O are present in both the crystal and boundary layer．but disappear in the melt． The structure of the growth solid—liquid boundary layer is similar to that of BGO crysta1．In the melt，the long·range order structure of the crystal disappears．Finally，we obtained the thickness of the growth solid·liquid boundary layer of BGO crystal for