BrO3^-等溴类物质在长江水氯化过程中的形成.pdfVIP

中国环境科学 2007，27(6)：806--810 China Environmental Science BrO3-等溴类物质在长江水氯化过程中的形成 黄 鑫，高乃云 ，卢 宁(同济大学污染控制与资源化研究国家重点试验室，上海200092) 摘要：研究长江上海段原水中Br在氯化过程中的产物，以BrO3 、Br和三卤甲烷(THMs)为主要测定物，考察pH值、氯投加量和Bf浓度对三 者生成量的影响．研究表明,BrO3一在氯化过程中的形成缓慢，其生成量与氯投加量正相关，常规消毒条件下不会超过10gg／L的国家标准．在余氯 充足的情况下，增加Br-浓度主要增加了总有机溴ffOB~，而BtO3生成量基本不变，弱碱性条件有利于TOBr的生成；TttMs和TOBr有一定相 关性，Br-浓度升高将导致THMs生成量增加，其中三氯甲烷浓度下降，混合取代的THMs浓度先增加后减少，三溴甲烷浓度显著上升． 关键词：BrO3；三卤甲烷(THMs)；氯化；长江原水 中图分类号：X131．2 文献标识码：A 文章编号：1000—6923(2007)06—0806—05 Formation ofBrOa—et ai．bromine kind maHer in chlorination water of Yangtze River．HUANG Xin，GAO Nai-yun’， Lu Ning(State Key Laboratory of Pollution Control and Resource Reuse，Tongji University,Shanghai 200092，China)． China Environmental Science，2007，27(6)：806~810 Abstract：The products of Br—in chlorination process in Shanghai section raw water of Yangtze River was studied．using BrO3一，Br-and trihalomethanes(THMs)as the main detection matter．The influence of pH value，chlorine adding amount and Br—concentration on the production amounts of these three products Was explored．The formation of BrO1一．m chlorination process Was slow relatively．Its production amount related positively with chlorine adding am ount，could not exceed the national l Ogg／L standards under the rule disinfection condition．Under the condition of residual chlorine satisfying，increasing Br concentration increased mainly the amount of total organic bromine(TOBr)，whereas BrO3一 production am ount Was not changed basically．W ak alkaline condition Was favorable to the formation of TOBr；THMs and TOBr had definite relationship．enhancing Br concentration would induce the increase of production am ount of trihalomethanes in which chlorofoWill concentration lowered,mixed substitute删 S increased first，then decreased。 bromoform increased markedly． Key words：bmmate(Br03)；trihalomethanes(THMs)；chlorination；Yangtze River raW water 饮用水源水中的Br-在常规混凝沉淀工艺中 究和报道．本研究以长江上