溶液法制备聚丙烯酸（钠）高吸水树脂及其影响因素分析.pdfVIP

安徽农业科学，Journal ofAnhui Agn．Sci．2008，36(12)：4813—4814，4931 责任编辑 孙红忠 责任校对 况玲玲 溶液法制备聚丙烯酸(钠)高吸水树脂及其影响因素分析 陈立贵(~igN工学院材料科学与工程学院，陕西汉中7230o3) 摘要 [目的]探索制备高吸水树脂的最佳工艺条件。[方法]以过硫酸钾为引发剂，N，N一一亚甲基双丙烯酰胺为交联剂，通过溶液法利用 部分中和的丙烯酸聚合成高吸水树脂。研究引发剂用量、交联剂用量和丙烯酸中和度对合成树脂吸水倍率的影响，确定制备高吸水树 脂的最佳工艺条件，并分析了合成高吸水树脂的保水性能。[结果]丙烯酸中和度对合成树脂吸水倍率的影响较大。随着丙烯酸中和度 和交联剂用量的增加，合成树脂的吸水倍率均呈先增后减的趋势。制备聚丙烯酸(钠)高吸水树脂的最佳工艺条件为：丙烯酸中和度 80％，引发剂用量0．16％，交联剂用量0．06％。[结论]合成的聚丙烯酸钠高吸水树脂具有较好的保水性能，在蒸馏水中的吸水倍率可达 592 g／g。 ‘ 关键词 丙烯酸；高吸水树脂；溶液法；吸水倍率；保水性能 ’ 中图分类号 TQ322．4 4 文献标识码 A 文章编号 0517—66l1(2008)12—04813—02 Prel~xation of Polyacrylk Acid(Soditlal1)High Water-absorbing Resin by Solution M~thod and Its Influencing Factors Analysis a}珏N Li-gui (College of Material Science and Engineering，Shaanxi University of Technology，Hanzhong，Shaanxi 723O03) Allstraet [Objective]rI11e research aimed to explore the optin~n tectmologieal conditions of prepa,~ high water-absorbing resin．【Method J WitIl potassium persulfate as initiator and nlethylene-bis—acrylamide as crosslinking agent，some neutralized acrylic acid(AA)were used to aggregate into high water-absorbing resin by solution method．rI11e effects of initiator dosage，crosslinking agent and the neutralization degree of AA on water absorbency ofthe synthesized resinwere studiedtocorrfinnthe optinmmtechnologicalconditions ofpreparing h岫 water-absorbing resin．Andthewater holdingperfor— rnance of high water-absorbing resin synthesized Was analyzed．1 Result J AA neutralization degree had a greater effect on water absorbency ofthe synthe— sized resin．WitIl the increasing ofAA neutralization degree and crosslinking agent dosage．water absorbency ofthe synthesized iesin 13oth showed the trend offirst increasing and then decreasing．rI11e optimum technological conditions of mpa~g polyaerylie acid(sodium)high water-absorbing resin were as follows：hA neutralization d