使用小波分析工业电解中铜阳极行为的电化学噪声.pdfVIP

Trans. Nonferrous Met. Soc. China 23(2013) 1854−1862 Electrochemical noise of copper anode behaviour in industrial electrolyte using wavelet analysis F. SAFIZADEH, E. GHALI Department of Mining, Metallurgy and Material Engineering, Laval University, Québec G1V 0A6, Canada Received 2 July 2012; accepted 27 November 2012 Abstract: Electrochemical noise (EN) data were measured during the dissolution and passivation of an Cu−Pb anode at 65 °C in 1 L industrial electrolyte containing 2 mg of gelatine and 4 mg of thiourea. The EN data corresponding to three stages or regions of active, pre-passive and passive on chronopotentiogram curve were analyzed by wavelet transform technique. The results reveal the 2 pitting type of localized corrosion form during both active and pre-passive stages under a constant current density of 215 mA/cm . During the passive stage, a general corrosion form accompanied by oxygen evolution was observed. Key words: electroctrochemical noise; corrosion; wavelet transform; copper; additives; chronopotentiometry of analyses, the morphology of deposit, the mechanism 1 Introduction of electrocrystallization, the preferred orientation of different electrodeposited elements and the crystal Various organic and inorganic additives are used growth proces