表面活性剂对钨酸铅低维粉体形貌的影响.pdfVIP

第37卷 第1期 人 工 晶 体 学 报 Vo1．37 No．1 2008年2月 JOURNAL OF SYNTHETIC CRYSTALS February．20o8 表面活性剂对钨酸铅低维粉体形貌的影响 杨玉国 ，王 卓 ，许建华 ，刘越华 ，曹树梁 (1．山东省科学院新材料研究所，济南250014；2．烟台大学环境和材料工程学院。烟台264005) 摘要：以钨酸钠和醋酸铅为原料，分别加以表面活性剂聚乙二醇200和十六烷基三甲苯溴化铵，用沉淀法合成出钨 酸铅纳米晶和菱形微晶。对样品进行x射线分析，结果显示样品结晶良好。对样品进行透射电子显微镜分析，结 果显示钨酸铅纳米晶和菱形微晶成形良好，且分散性良好、无团聚发生。讨论了表面活性剂对钨酸铅低维粉体形 貌的影响，认为PEG200对分散性良好的钨酸铅纳米晶的生成起了关键作用，而CTAB则促进了成形良好的菱形钨 酸铅微晶的生成。 关键词：钨酸铅；低维粉体；表面活性剂；形貌 中图分类号：O614 文献标识码：A 文章编号：1000-985X(2008)01-0240-03 Influence of Surfactants on Morphology of Lead Tungstate Crytalline YANG Yu-guo ，WANG Zhuo ，XU Jian-hua ， Yue-hua CAO Shu-liang ． (1．New Materials Research Institute of Shandong Academy of Sciences，Jinan 250014，China；2~Sch~I of Environment and Materials Engineering，Yantai University，Yantai 264005，China) (Received 5 June 2007，accepted16 July 2007) Abstract：Lead tungstate crytalline were synthesized by deposition，with lead acetate and natrium tungstate as starting materials．And the morphologies of lead tungstate crystal were different when different surfactants of polygycol 200 and cetyltrimethyl ammonium bromide(CTAB)were added in the experiments．The XRD pattern indicate that the well-crystalized lead tungstate crystals could be obtained under given synthetic condition．The transmission electron microscopy was used to study their morphologies．The experimental·results show that surfactant plays important role in the synthesization of lead tungstate crysta1． Key words：lead tungstate；particles；surfactants；morphologies 1 引