胺基化四钛酸材料吸附直接湖蓝5B性能.pdfVIP

第30卷第1期 南 京 工 业 大 学 学 报 (自然科 学版) Vol_30 No．1 2008年1月 JOURNAL OF NANJING UNIVERSITY OF TECHNOLOGY(Natural Science Edition) Jan．20o8 胺基化四钛酸材料吸附直接湖蓝5 B性能 年季强 ，俞 斌 ，王海平 ，武中林 ，沈树宝 ，杨文忠 (1．南京工业大学理学院，江苏 南京210009；2．南京工业大学制药与生命科学学院，江苏 南京210009) 摘 要：微波酸化K，Ti O ，正十二胺微波胺基化改性H2Ti O9，获得正十二胺柱撑的层状钛酸材料．研究了其作为 吸附剂，pH、初始染料质量浓度、吸附剂用量等因素对直接湖蓝5B偶氮染料吸附的影响，确定最佳条件．研究结果 表明：微波法改性钛酸钾材料，具有良好的吸附性能；pH为2～4，脱色时间为40 min，吸附剂用量为1 g／L，温度为 40℃时饱和吸附量最大，达到1 333 mg／g，吸附等温式能较好地符合Langmuir和Freundlich方程模型参数． 关键词：胺基化四钛酸；微波辐射；层间距；吸附；脱色 中图分类号：O611 文献标识码：A 文章编号：1671—7627(2008)01—0007—04 Adsorption properties for direct sky blue 5 B by the aminated tetratitanate whisker NIAN Ji-qiang ，YU Bin ，WANG Hai—ping ，WU Zhong—lin ，Shen Shu—bao ，Yang Wen—zhong (1．College of Sciences，Nanjing University of Technology，Nanjing 210009，China； 2．College of Life Science and Pharmaceutical Engineering，Nanjing University of Technology，Nanjing 210009，China) Abstract：H2 Ti4 O9 was synthesized by microwave acidification from potassium tetratitanate(K2 Ti4 O9)whiskers， then the aminated tetratitanate acid was obtained by the intercalation of n—dodecylamine using microwave irradia— tion．The adsorption property on various conditions such as pH value，initial dyes concentration and adsorbent dos— age were investigated and optimal experimental conditions were obtained．The results indicated that the rate of the reaction of layered tetratitanate modification was greatly enhanced under microwave radiation．The grafted aminated tetratitanate acid had a higher adsorption capacity and adsorption speed for removing dyes from dye wastewater．The greatest adsorption of dyes on aminated tetratitanate acid at pH of 2～4，the adsorption time of 40 min，the dosage 1 g／L and at 40℃．The former’S adsorption capacities were 1 333 mg／g．the