碱性过硫酸钾氧化- 气相分子吸收光谱法测定水中总氮.pdf

22 4 2010 8 - 1 2 1 莫怡玉, 茅丽秋 , 吴卓智 ( 1. 湛江市海洋与渔业环境监测站, 广东 湛江 524039; 2. 湛江市港务管理局环境监测站, 广东 湛江 524027) : - , , , NaOH, 0 g~ 20. 0 g, 0. 016 mg/L, RSD 1. 5%, 99. 2% ~ 102%, 3. 3% : ;;; : O657. 3 : B : 1006-2009( 2010)04- 0047- 03 TotalNitrogen Determ ination inW ater by GasM olecular Absorption Spectrometry w ith A lkaline Potassium Persulfate Oxi ation 1 2 1 MO -iyu, MAO Li-qiu, WU Zhuo-zhi ( 1. Zhanj iang Ocean and F ishery EnvironmentalM onitoring Station, Zhanjiang, Guangdong 524039, China; 2. Zhanj iang Port uthority Environm entalM onitoring Station, Zhanj iang, Guangdong 524027, China) Abstract: Total nitrogen in waterwas determ ined by gasmolecular absorption spectrom etryw ith potassium persulfate oxidation. The detection used polyfluortetraethylene digestive tubeswithwhorlcap instead of colormi e- ter tubes, volum e calibration byweighingmethod and increasedNaOH dosage. The interference and its elmi inate measurementwere discussed. A good linearity was in range from 0 g to 20. 0 g. The detection lmi it was 0. 016mg/L. RSD of parallel standard solution was 1. 5%. Spiked recoveries of samples were between 99. 2% and 102%. Expanded uncertainty of test resultswas 3. 3% . Key wor s: Total nitrogen; Alkaline potassium persulfate; Gas molecular absorption spectrometry; W ater quality [5] ( , ), , , , [ 1- 3] - NaOH , [4] ; - - [ 5- 6] [7] (, , ; ,); NaOH (2~ 4),