催化裂化油浆合成沥青树脂的反应性能.pdfVIP

2008年 第32卷 中国石油大学学报(自然科学版) Vo1．32 No．1 第1期 Journal of China University of Petroleum Feb．2008 文章编号：1673—5005(2008)ol-0128-05 催化裂化油浆合成沥青树脂的反应性能 郭燕生，陈丽丽，查庆芳，吴明铂 (中国石油大学重质油国家重点实验室，山东东营257061) 摘要：采用溶剂萃取对催化裂化油浆进行了芳烃富集，并分别以油浆和富芳烃组分为原料合成了沥青树脂。利用族 组成分析和Fvr—IR、1H—NMR、13C—NMR测试对比了催化裂化油浆芳烃富集前后的原料组成差别，通过合成B阶沥青 树脂的反应差异考察了催化裂化油浆的反应性能。结果表明，催化裂化油浆中饱和分的含量较高，均匀性差；而溶 剂萃取后的催化裂化油浆富芳烃组分芳烃含量较高，均匀性较好。溶剂富集芳烃提高了催化裂化油浆的反应性能。 关键词：催化裂化油浆；合成反应；沥青树脂；油浆利用 中图分类号：TQ 342．86 文献标识码：A Reactivity of FCC slurry for synthesizing pitch resin GUO Yan—sheng，CHEN Li—li，ZIIA Qing—fang，wU Ming—bo (Key Laboratory of Heavy Oil Processing in China University of Petroleum，Dongying 257061， Shandong Province，China) Abstracts：Aromatic—enriched components were obtmned from FCC slurry by means of solvent extraction，Both original FCC slurry and aromatic—enriched components were employed to synthesize pitch resin．The properties of raw materials were analyzed using group composition analysis，infrared spectrum and nuclear magnetic resonance spectrum method．The reactivity of FCC slurry to synthesize B—stage pitch resin was investigated through the gynthesis of pitch resin，The results show that the concen— tration of saturates in original FCC slurry is higher than aromatic—enriched components，the homogeneity is bad and the compo— sition of FCC slurry is complex．The reactivity of raw materialS was greatly improved after solvent extraction． Key words：FCC slurry；synthetic reaction；pitch resin；solvent extraction ‘ 流化床催化裂化(FCC)油浆中含有大量的2～ 供依据。 4环芳烃，馏程主要集中在300～500℃。FCC油浆 1 实 验 体系是制备多种炭材料的良好原料 J。根据沥青 树脂的合成机理推断 ，FCC油浆可以制备优质 1．1 原 料 的沥青树脂。FCC油浆中的