低温固相合成掺铜磷酸锌钠及其数据挖掘的研究.pdfVIP

第38卷第2期 涂料工业 Vo1．38 No．2 2008年2月 PAINT＆COATINGS INDUSTRY Feb．2008 低温固相合成掺铜磷酸锌钠及其数据挖掘的研究 宋宝玲，陈 霞，廖 森，吴文伟，王天顺 (广西大学化学415_r-_学院，南宁530004) 摘 要：以ZnSO ·7H O，Na PO ·12H 0为原料，硫酸铜为掺杂剂，以PEG一400为表丽活性剂，经低热固相反应 合成得到掺杂铜的磷酸锌钠纳米晶。用产物XRD图谱数据计算得到的结晶度作为试验的考察指标，试验中应用了均 匀设计试验法及数据挖掘技术，征数据挖掘成果的指导下进行了试验。试验结果表明，用最优工艺条件合成得到的产 物为52 nm的掺铜NaZnPO ·H O，结晶度为98．80％，与数据挖掘得到的最佳结果相吻合。 关键词：磷酸锌钠；固相反应；均匀设计；数据挖掘技术 中图分类号：TQ 628．3 文献标识码：A 文章编号：0253—4312(2008)02—0021—04 Synthesis and Crystallization Study of Cu 一Doped Sodium Zinc Phosphate via Solid State Reaction Song Baoling，Chen Xia，Liao Sen，Wu Wenwei，Wang Tianshun (School of Chemistry and Chemical Engineering，Guangxi University，Nanning 530004，China) Abstract：Cu“ 一doped sodium zinc phosphate was studied，the title product was prepared successfully with ZnSO4·7H2O，Na3PO4·12H20 and LiCO3 as raw materials via solid state reaction at room temperature and PEG一400 as template via low heat solid state reaction．Crystallization of the products calculated with XRD data of the products was used as testing indexes，and application of uniform experimental design as well as data mining technology were applied in the test．The synthesis tests were done，which were directed with the results of data mining technology．The test results indicated that the product synthesized with the optimal technical condition was NaZnPO4 H2O with size of 52 nm and crystallization of 98．8％ that accorded with the optimization result of data mining． Key Words：sodium znic phosphate；solid state reaction；uniform design；data mining technology 纯；聚乙二醇一400(PEG一400)：工业品。D／Max2005DC型x 0 引 言 一