关于国标中食品包装用聚苯乙烯树脂挥发物测定的几点改进建议.pdfVIP

广 东 化 工 2008年 第2期 54 www．gdchem．com 第35卷 总第178期 关于国标中食品包装用聚苯乙烯树脂挥发物 测定的几点改进建议 谭曜，陆机芳，王群威 (宁波出入境检验检疫局，浙江 宁波 315012) 【摘 要】在使用国标GB／T 5009．59—2003对食品包装用聚苯乙烯树脂挥发物进行测定时，发现该实验方法存在重现性 差的问题，样品在溶解操作过程中，玻璃棒容易粘附样品而损失样品质量；样品在低压真空，温度在138-140℃干燥过 程中容易起泡、暴沸喷出，造成实验失败。通过对国标GB／T5009．59—2003的几点改进，让样品自然溶解、适当加大烧杯、 使用超声波适当处理样品浓稠溶液等方法大大提高了实验的重显性和成功率。 【关键词】食品包装；聚苯乙烯；挥发物；改进建议 Emendatory Suggestions on Determination of Volatile Compounds of Ployethylene Resin for Food Packaging in GB Tan Yao，Lu Jifang，Wang Qunwei (Ningbo Entry—Exit Inspection and Quarantine Burear,Ningbo 3 1 50 1 2，China) Abstract：In the determination of volatile compounds of p1oyethethy1ene resin for food packaging in GB／T 5009．59—2003，it exited some shortcomes on the method．Repeatability of the test results was 1o w．the samples lost its qualityies easily when they were stirred and adhered on the glass stick，the test was caused failure because the samples bubbled and bursted forth easily dudng the dry proceeding at the condition of low air pressure and temperature about 1 38～1 40 ℃．While several emendatory suggestions on GB／T 5009．59—2003 were introduced，the repeatability and successful rates were improved largely，such as the samples dissolving naturally,enlarging beaker properly, dealing with concentrated solution of the samples with the ultrasonic instrument and SO on． Keywords：food packaging；ployethylene；volatile compound；emendatory suggestion 苯乙烯系树脂是指以苯乙烯为单体的均聚物、共聚物及其 是聚苯乙烯树脂中含有苯乙烯、乙苯等对人体有害的挥发物成 掺混物等一大类热塑性树脂。其中聚苯乙烯产品产量居首，发 分，因此测定聚苯乙烯树脂挥发物含量是判定聚苯乙烯树脂是 展最早。聚苯乙烯的工业生产方法，一般为本体聚合和悬浮聚