鱼粉品质的近红外反射光谱快速检测方法.pdfVIP

农业机械学报 第 36 卷第 5 期 2005 年 5 月 鱼粉品质的近红外反射光谱快速检测方法 牛智有韩鲁佳苏晓鸥杨振海 E摘要】 利用近红外光谱分析技术检测 145 个鱼粉佯品化学成分，其中 115 个作为定标集，其余 30 个作为检 验集。采用偏最小二乘法(PLS)建立定标模型，并对原始光谱进行预处理。结果表明，以一阶导数和 9 点卷积平滑预 处理效果最佳。用所建立的定标模型对检验集样品进行成分预测，并对预测值与化学分析值之间进行F 检验，结果 表明，在置信度为 99%下，除钙之外，其他成分均为高度显著。近红外光谱分析技术可以检测鱼粉中的水分、粗蛋 白、粗脂肪、粗灰分、总磷和盐分，但钙的预测结果不理想。 关键词z 鱼粉品质检测光谱分析 中固分类号: S379. 1; S963. 32+ 1 文献标识码:A Quality Prediction of Fish Meal by Near Infrared Reflectance Spectroscopy Niu Zhiyou 1 Han Lujia 1 Su Xiaoou 2 Yang Zhenhai 3 (1. China Agricultural University 2. National Feed Quality Supervision and Test Center(Beijing) 3. Animal H usbandry and Veterinary Bureau. Agriculture Ministry) Abstract Near infrared reflectance spectroscopy (NIRS) was used to predict chemical composition of 145 fish meal samples. using 115 of all samples as a calibration set. and others as validation set. The NIRS calibration models were developed using the partial least squares (PLS) regression technique. Initial spectrum was pretreated. and the first derivative with Savisky-Golay smoothing were the best method. The chemical composition of 30 fish meal samples for validation set were predicted by NIRS calibration mode l. The relationship between predicted and chemical value was F -tests. and which showed that all ingredients. except for calcium. were of high significance with confidence degree 99 %. It was concluded that NIRS can be used as a method to predict the moisture. crude protein. crude fat. crude ash. phosphorus and salt as NaCl in fish meal ex