原创力文档comparative study between d2ehpa and cyanex 272 as extractants of mn(ii) from a leached liquor produced by reductive leaching of a pyrolusite ore with so2d2ehpa cyanex 272之间的比较研究萃取剂锰(ii)的淋滤酒由用二氧化硫还原浸出软锰矿的矿石.pdfVIP
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comparative study between d2ehpa and cyanex 272 as extractants of mn(ii) from a leached liquor produced by reductive leaching of a pyrolusite ore with so2d2ehpa cyanex 272之间的比较研究萃取剂锰(ii)的淋滤酒由用二氧化硫还原浸出软锰矿的矿石
Engineering, 2012, 4, 526-531
/10.4236/eng.2012.49067 Published Online September 2012 (http://www.SciRP.org/journal/eng)
Comparative Study between D2EHPA and Cyanex 272 as
Extractants of Mn(II) from a Leached Liquor Produced by
Reductive Leaching of a Pyrolusite Ore with SO2
Roberto Pérez-Garibay, Javier Martínez-Jiménez,
Alejandro Uribe-Salas, Antonia Martínez-Luévanos
Centro de Investigación y de Estudios Avanzados del IPN, Ramos Arizpe, México
Email: roberto.perez@.mx
Received June 29, 2012; revised July 27, 2012; accepted August 9, 2012
ABSTRACT
This paper compares the efficiency of D2EHPA and Cyanex 272 to extract the divalent manganese cation from an ac-
tual leaching solution obtained by reductive leaching of a low-grade pyrolusite ore, using SO2 gas. The studied variables
were the extractant concentration in the organic phase, the pH of the leached liquor and the volume ratio between or-
ganic phase and leached liquor. It was observed that D2EHPA is a better extractant than Cyanex 272. Therefore, with
the best experimental conditions found, both extractants reach a manganese recovery around 95% with five extraction
stages conducted under the following conditions: 25˚C, O/A = 2, 10% volume of extractant concentration in the organic
phase, pH of the leached liquor before the mixing between 8 and 8.5, and one minute of mixing time for each extraction
stage.
Keywords: Manganese Solvent Extraction; Manganese Leaching; Manganese; Pyrolusite
1. Introduction zinc from leach liquors of cobalt is the most common
objective of manganese extraction studies [3-7]. How-
In last decades the
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