effect of rare earth y on properties of nanosized 90w-7ni-3fe composite powder fabricated by spray drying-hydrogen reduction90年稀土y对性质的影响纳米w-7ni-3fe复合粉喷雾减少drying-hydrogen臆造出来的.pdfVIP

Hindawi Publishing Corporation Journal of Nanomaterials Volume 2008, Article ID 459093, 4 pages doi:10.1155/2008/459093 Research Article Effect of Rare Earth Y on Properties of Nanosized 90W-7Ni-3Fe Composite Powder Fabricated by Spray Drying-Hydrogen Reduction Y.-Z. Ma, Liu Wensheng, Huang Baiyun, and Fan Jinglian State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China Correspondence should be addressed to Y.-Z. Ma, yunzhum@163.com Received 6 July 2007; Accepted 11 January 2008 Recommended by Jun Lou (W,Ni,Fe) composite oxide powder synthesized by spray drying was reduced at 700◦C for 90 minutes in H2 atmosphere. The effect of rare earth Y on H2 reduction of (W,Ni,Fe) composite oxide powder was studied. Phase composition, crystalline size, and particle morphology of the reduced powder have been measured by X-ray diffraction and scanning electron microscope (SEM). Fsss particle size and special surface area of the reduced powder were also measured and analyzed. The result showed that new phase Y(Ni0.75W0.25 )O3 appeared in the reduced powder and particle morphology was nearly spherical or polyhedron by Y additions. The higher the rare earth element content was, the bigger the influencing on particle morphology was. When the rare earth Y content was under 0.8%, with the increase of the rare earth element content, dBET , Fsss, and crystal sizes of the reduced powder decreased greatly. Copyright © 2008 Y.-Z. Ma et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 1. INTRODUCTION (W,Ni,Fe) composite ox