高镁锂比盐湖卤水镁锂分离工艺-中南大学学报.PDF

第 40 卷第 1 期 中南大学学报( 自然科学版) Vol.40 No.1 2009 年 2 月 Journal of Central South University (Science and Technology) Feb. 2009 高镁锂比盐湖卤水镁锂分离工艺 徐 徽，许 良，陈白珍，石西昌，杨 鑫 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：以高镁锂比盐湖卤水为原料，进行镁锂分离的工艺研究。分别用氨和碳酸氢铵进行二段沉镁，卤水中98% 的 Mg2+ 以氢氧化镁和碱式碳酸镁形式沉淀分离出去，溶液经浓缩结晶析出氯化铵后, 再用氢氧化钠进行深度除 镁，很好地实现镁锂的分离。研究 NaOH 的加料方式、浓度、加料速度、终点pH 值、反应温度及反应时间对除 镁效果的影响。实验结果表明：在 NaOH 溶液浓度为 10 mol/L，加料速度为 0.3~0.5 mL/min，pH =12 ，温度为 25 ℃，反应时间为20~30 min 的条件下，母液中Mg2+可以除尽，为后续工序制备碳酸锂创造了有利的条件。 关键词：盐湖卤水；氢氧化镁；溶解度；浓缩 中图分类号：TQ123.4 文献标识码：A 文章编号：1672−7207(2009)01−0036−05 Separating technique for magnesium and lithium from high Mg/Li ratio salt lake brine XU Hui, XU Liang, CHEN Bai-zhen, SHI Xi-chang, YANG Xin (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: Using salt lake brine with high magnesium/lithium ratio as raw material, the process of separating lithium from magnesium in the brine was studied. The technological parameters of the process were obtained. Two precipitation steps were studied in the process using ammonia and ammonium bicarbonate as the precipitator. About 98% of Mg2+ in the brine is precipitated as magnesium hydroxide and the light magnesium carbonate is precipitated respectively. NH4Cl is obtained while the solution is concentrated. And then, the magnesium ion remained in the solution is further extracted out by adding NaOH. The effect of some parameters of the process were studied and the effects of adding method of reagents, concentration of NaOH solution, adding rat