不同组成Pt-Co合金催化剂的电催化还原H2O2性能研究.docVIP

不同组成Pt-Co合金催化剂的电催化还原H2O2性能研究 摘要：本论文首先通过浸渍-还原法分别制备出了以碳粉VulcanXC-72R为载体，Pt含量为20%的Pt/C催化剂及Pt、Co含量各10%的Pt-Co/C催化剂。通过循环伏安曲线和线性扫描伏安曲线比较两种催化剂的电催化性能，从而判断出可以用Pt-Co/C催化剂来代替Pt/C催化剂，以达到减少贵金属的用量，降低催化剂制作成本的目的。再维持Pt的含量为10%，制备出Co含量分别为5%、15%、20%、25%的一系列Pt-Co/C催化剂。比较不同组成催化剂的催化性能，寻找最优配比。实验结果发现Pt含量为10%，Co含量为15%的Pt-Co/C催化剂催化性能最好。另外，将CNTs取代碳粉作为载体，同样发现10%的Pt与15%的Co形成的催化剂催化效果最好。比较相同组成、不同载体催化剂的循环伏安曲线发现，以CNTs为载体制备的Pt-Co/CNTs催化剂的还原峰电流比以VulcanXC-72R为载体的催化剂有所降低，但其还原峰电位却有所增大。10947 关键词： 燃料电池；铂钴合金；阴极催化剂；电还原；双氧水 Study of different composition of Pt-Co alloy catalyst for the electrocatalytic reduction performance of H2O2 Abstract: In this paper, we prepared Pt/C(containing 20% Pt) and Pt-Co/C (metal content=10% in either case) by the impregnation-reduction method. After comparing the two catalystsrsquo; electrocatalytic performance through cyclic voltammetry and linear sweep voltammetry curves, we found Pt-Co/C catalysts can be used instead of Pt/C catalysts. So it is possible to achieve the goal of reducing the amount of the noble metal and production costs. Then, we prepared a series of Pt-Co/C catalysts by the same method, such as Pt-Co1/C(containing 10% Pt and 5% Co), Pt-Co2/C(containing 10% Pt and 10% Co), Pt-Co3/C(containing 10% Pt and 15% Co), Pt-Co4/C(containing 10% Pt and 20% Co) and Pt-Co5/C(containing 10% Pt and 25% Co). Comparing the catalytic performance of all the catalysts of different proportions can help us to find the optimal ratio. The experimental results show that the Pt-Co3/C(containing 10% Pt and 15% Co) catalyst has the best catalytic performance. In addition, CNTs was used in this paper as carrier of catalysts. We also found that the optimal ratio is the Pt-Co3/CNTs(containing 10% 3.2.2 碳纳米管负载不同组成铂钴合金催化剂的性能分析24 3.3 碳粉负载催化剂与碳纳米管负载催化剂的性能比较27 3.3.1 Pt20%/C与Pt20%/CNTs催化剂的性能比较27 3.3.2 Pt10%Co15%/C与Pt10%Co15%/CNTs催化剂的性能比较30 4 结论33 致谢35 参考文献36 1 绪论 1.1 引言 燃料电池是一种直接将化学能转化成电能的装置，由于其不受卡诺循环的限制，因此具有更高的能量转换效率。传统的在陆地上使用的燃料电池通常以空气中的氧气为氧化剂。在无空气环境下(水下和太空)工作的燃料电池，则常采用液态氧或压缩氧气，这两种氧的携带