典型有机氮类化合物存在时的加氯消毒控制方法.PDFVIP

典型有机氮类化合物存在时的加氯消毒控制方法* 陶辉，陈卫，陈亮，冯博 河海大学环境学院，江苏 南京，210098 摘要：氯是目前最为常用的消毒剂，当其投加到水中后不但会与氨产生折点氯化 反应，还会与有机氮类化合物反应生成不具有消毒效果的有机氯胺，从而对经典 的折点氯化反应产生影响。采用在水中经常检出的甘氨酸作为典型有机氮类化合 物，研究了其对自由氯生成特性的影响。研究显示，有机氮类化合物会使得自由 氯出现时的 Cl :N 大大延迟，并且自由氯出现时的 Cl :N 以及由有机氮化合物所 2 2 引起的额外耗氯量均与有机氮类化合量具有良好的线性关系。但由于氯与氨氮、 有机氮类化合物反应时化学计量比不同，因此不采用总氮作为加氯量的控制指 标。并在上述研究的基础上提出了存在有机氮类化合物时的加氯控制方法。 关键词：消毒，液氯，有机氮类化合物，甘氨酸 Chlorine Dosage Control Method for Water with Organic Nitrogenous Compounds and Ammonia in Chlorination Tao Hui, Chen Wei, Chen Liang, Feng Bo College of Environment, Hohai University, Nanjing, 210098, China Abstract: Chlorine is the most widely used disinfectant in water and wastewater disinfection. Besides the breakpoint chlorination of chlorine with ammonia, chlorine can also react with organic nitrogenous compounds and form organic chloramines which have no biocidal ability, thus effect the classical breakpoint chlorination. By using glycine which is usually detected in water and wastewater, the free chlorine formation characteristics were studied. The results showed that organic nitrogenous compounds delayed the Cl2 :N ratio at which free chlorine first present. This Cl2:N ratio and the extra chlorine consumed by organic nitrogenous compounds was related to the organic nitrogenous compounds contents. However, due to the different stoichiometric ratio of chlorine with ammonia and nitrogenous compounds, the TN could not be used as control parameter in chlorination. Based on the experimental results, chlorine dosage control method in water with organic nitrogenous compounds was proposed. 在地表水体中有机氮类化合物含量，与氨氮的含量相当，有时甚至超过氨氮 含量[1,2] 。当向水