the peroxidaseh2o2 system as a free radical-generating agent for gelling maize bran arabinoxylans rheological and structural propertiesperoxidaseh2o2系统作为一个自由radical-generating剂胶凝玉米麸皮阿糖基木聚糖流变和结构属性.pdfVIP
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the peroxidaseh2o2 system as a free radical-generating agent for gelling maize bran arabinoxylans rheological and structural propertiesperoxidaseh2o2系统作为一个自由radical-generating剂胶凝玉米麸皮阿糖基木聚糖流变和结构属性
Molecules 2011, 16, 8410-8418; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Communication
The Peroxidase/H O System as a Free Radical-Generating
2 2
Agent for Gelling Maize Bran Arabinoxylans: Rheological and
Structural Properties
Ana L. Martínez-López 1, Elizabeth Carvajal-Millan 1,*, Jaime Lizardi-Mendoza 1,
Yolanda L. López-Franco 1, Agustín Rascón-Chu 2, Erika Salas-Muñoz 3, Cécile Barron 4 and
Valérie Micard 4
1 CTAOA, Laboratory of Biopolymers, Research Center for Food and Development, CIAD, AC.,
Hermosillo, Sonora 83000, Mexico
2 CTAOV, Research Center for Food and Development, CIAD, AC., Hermosillo, Sonora 83000,
Mexico
3 Chemistry Faculty, Autonomous University of Chihuahua, Chihuahua 31125, Mexico
4 U.M.R. Ingénierie des Agropolymères et des Technologies Emergentes. SupAgro / INRA,
2 Pl Viala Montpellier 34060 cedex 01, France
* Author to whom correspondence should be addressed; E-Mail: ecarvajal@ciad.mx;
Tel.: +52-662-289-2400; Fax: +52-662-280-0421.
Received: 18 August 2011; in revised form: 22 September 2011 / Accepted: 22 September 2011 /
Published: 10 October 2011
Abstract: The oxidative gelation of maize bran arabinoxylans (MBAX) using a
peroxidase/H O system as a free radical-generating agent was investigated. The
2 2
peroxidase/H O system led to the formation of dimers and trimer of ferulic acid as
2 2
covalent cross-link structures in the MBAX network.
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