无溶剂体系中非均相催化剂催化环己烷氧化反应研究.pdfVIP

第22卷 第6期 分 子 催 化 V01．22．No．6 2008年 l2月 JOURNALOFMOLECULARCATALYSIS(CHINA) Dec． 2008 ArticleID：1001—3555(2008)0643513-06 StudyofCatalyzedOxidationofCyclohexaneinaSolvent-freeSystem usingauniqueCombination oftwoHeter0gene0usCatalysts YANGDan—hong ，ZHAOWen-jun ，GAOLin (a．XinfiangTechnicalInstituteofPhysicsandChemistry，ChineseAcademyofScience，Urumqi830011，China； b．GraduateSchooloftheChineseAcademyofScience，Beifing100049，China) Abstract：Styrene—maleicanhydridecopolymer(SMA)anchoredN—Hydr0xyphthalimide(NHPI)andCo／ZSM-5werepreparedand characterizedbyFT—IR ，XRD respectively．W ithtwoheterogeneouscatalyststogetherin asolvent—free system theeffectsofvital ， processparametersontheoxidationofcyclohexanewerestudied．Undertheoptimizedconditions．the26．8％ oftheconversionofcy— clohexane，71．6％，10．9％ and2．6％oftheselectivityofKA0ij(themixtureofcyclohexanoneandcyclohexano1)，adipicacidand cyclohexylhydroperoxide(CHHP)wereobtained．Whenthetesttemperaturerangedrfom393Kto433K，thereactionrateconstantK andreactiontemperatureThadauArrheniusrelationshipwiththelinearcorrelationcoefficientof0．9878，itcanbeexpressedas：InK 。 ： 一 3012／T+ 1．279．Thestabilitystudyilluminatedthehighthermalstabilityofthetwoheterogeneouscatalysts．beingreusedforat leastfivereactioncycleswithoutconsiderablelossofreactivity． Keywords：SMA anchoredNHPI；Co／ZSM-5；cyclohexane；heterogeneousoxidation CLC number：0643．32 Document：A Thesele