功能化对石墨纳米片MnO2复合材料性能的影响范玉姣.pdfVIP

网络出版时间：2017-09-26 12:05:34 网络出版地址：/kcms/detail/11.2172.TQ1205.030.html 功能化对石墨纳米片/MnO2 复合材料性能的影响 范玉姣 ，焦文强，黄成德 （天津大学化工学院，天津 300350） 摘要：采用氨基芘、CTAB、芘羧酸不同酸碱性的有机小分子使石墨纳米片表面 功能化，其中，芘羧酸可以对石墨纳米片表面进行非共价键功能化，增大石墨纳 米片间的间距，将其剥离成单层、双层或者多层；使 MnO2 在石墨纳米片材料上 的负载更加均匀。电化学测试结果显示，经芘羧酸修饰的石墨纳米片/MnO2 复合 材料的比电容能达到 215 F/g ，相较于其他2 种(Amin、CTAB)修饰的复合材料比 电容能分别高出81%和 44% ，经4000 次循环后容量几乎无衰减，6000 次后，电 容保持率仍为 81%。 关键词：石墨纳米片；MnO ；芘羧酸；功能化；超级电容器 2 中图分类号：O646.54 文献标志码：A Effect of functionalized on the performance of graphite nanosheet/MnO2 compound FAN Yu-jiao JIAO Wen-qiang HUANG Cheng-de (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350 ，China) Abstract: The surface of the graphite nanosheets was functionalized by three small organic molecules(Amin, CTAB, PCA). Among them, PCA could make graphite nanosheets functionalize. The graphite nanosheets is stripped into monolayer, double or multilayer. the loading of MnO2 on the graphite nanosheets material is more uniform. The electrochemical test results show that the specific capacitance of the composites modified by PCA can reach 215 F / g, which is 81% and 44% higher than that of the other two (Amin, CTAB). After 4000 cycles , the capacity almost does not change. After 6000 times, the capacitor retention rate is still 81%. Key words: the graphite nanosheets ；MnO2 ；PCA ； functionalized ；supercapacitors