大枣多糖铁Ⅲ复合物的合成及一般性质研讨.pdfVIP

大枣多糖铁（Ⅲ）复合物的合成及一般性质研究 汤春妮， 王花， 樊君， 郭璞 （西北大学化工学院，陕西西安 710069） 摘要：本文用大枣多糖与铁(Ⅲ)合成了大枣多糖铁(Ⅲ)复合物(JPIC)，并研究了JPIC 的一般性质和合成工艺 条件。用水提法从工业枣渣中提取大枣多糖；在碱性条件下，大枣多糖溶液与三氯化铁溶液反应合成JPIC ； 测定JPIC 的一般理化性质；用邻菲罗啉分光光度法测定产物中含铁量；研究反应pH值、催化剂量、反应温 度对合成的影响。结果表明，JPIC是无定形红棕色粉末，易溶于水；JPIC 的水溶液在pH值3～12范围内具有 特别的稳定性且不存在游离的Fe3+ ；在抗坏血酸存在下，JPIC 中的铁在2.5h 内被完全还原；最佳反应pH值、 催化剂量、反应温度分别为pH8.0 、0.5g、80℃。JPIC有望开发成为一种新型的口服补铁剂。 关键词：大枣多糖；大枣多糖铁复合物；补铁剂；理化性质；合成工艺 中图分类号：R914.5 文献标识码：A 文章编号： Synthesis and physicochemical properties of jujube polysaccharide-Fe (Ⅲ) complex TANG Chunni, WANG Hua, FAN Jun, GUO Pu (Department of chemical engineering, Northwest University, Xi’an710069, Shaanxi, China) Abstract: Jujube polysaccharide-Fe (Ⅲ) complex (JPIC) was synthesized with jujube polysaccharide and Fe (Ⅲ). Physicochemical properties and synthetic conditions of JPIC were investigated. Jujube polysaccharide was extracted from the industrial jujube residue; JPIC was synthesized with jujube polysaccharide and FeCl3 under the alkaline condition; physicochemical properties was investigated through qualitative test、stability test、hydrolysis test and reduction test; the content of Fe (Ⅲ) in JPIC was determined by UV with the color reagent of ophenanthroline; the effects of reaction pH value、quantity of catalyst、reaction temperature were studied. The results showed that: JPIC was brownish red and shapeless powder; it could dissolve 3+ in water easily; its solution was very stable at the pH from3 to 12 and didn’t exist free Fe ; Fe (Ⅲ) could be completely reduced to Fe ( Ⅱ) in the presence of ascorbic acid in 2.5 hours; the best reaction pH value, qu