黄河口表层沉积物多环芳烃污染源解析研究 Source Apportionment of PAHs in Estuarine Sediments from the Yellow River.pdfVIP

环境科学研究 ResearchofEnvironmental 第2l卷第5期 Seiences V01．21，No．5，2008 黄河口表层沉积物多环芳烃污染源解析研究 刘宗峰1，郎印海H，曹正梅2，马启敏1 1．中国海洋大学环境科学与工程学院，山东青岛266100 2．青岛市环境保护局，山东青岛266003 摘要：利用气相色谱一质谱联用仪对黄河口表层沉积物中25种多环芳烃进行了分析．结果显示：沉积物中埘(PAHs)为 48．56—277．12 ng，g，平均值为122．92 然气燃烧排放、石油污染、焦炉燃烧排放三大污染源，其中石油污染贡献最大(占74．5％)，而交通燃油和天然气燃烧排放、焦 炉燃烧排放所占比例相对较小。分别为12．8％和12．7％． 关键词：多环芳烃；源解析；因子分析；多元线性回归；表层沉积物 中图分类号：X52 文献标志码：A 文章编号：1001—6929(2008)05—0079—06 in Source OfPAHsEstuarineSedimentsfromtheYellowRiver Apportionment L[U Yin·h1，CAO Zong-fen91，LANG Zheng-mei2，MAQi-min‘ of of EnvironmentalScienceand 266100。China 1．CoHege Engineering，OceanUniversityChina，Qingdao of Protectionof 2．BureauEnvironmental 266003，China Qingdao，Qingdao Abstract：Concentrationsof25 aromatic surfacesediments fromtheYeUowRiver we肥 eoHected polyeyclic hydrocarbons(PAHs)in Estuary measuredGC-MS．TheresultsshowedthatthetotalconcentrationsofPAHsinthesedimentsvariedfrom48．56 to277．12 by ng／g ng／g concentrationwas122．92 incm∞thattotalPMisconcentrationswereatlowerlevel torelevantareas (average ng／g)，which compared worldwide．Theof PAHsWaft the25individual was high．Among proportion2—3-ring quite PAHs。naphthalenehighest。andphenanthren，1一 and werealso ratiosrefittedamixedPAH of and methylnaphthalene2-methylnaphthaleneprevalent．Thediagnostic inputpatternpetrogemc insediments．Thefactor