[化学]富勒烯 Spherical Aromaticity of Fullerenes.pdfVIP

Spherical Aromaticity of Fullerenes 肖作 2005.10.28 Introduction 亲电取代反应 E E+ E+ Questions What are suitable aromaticity criteria for fullerenes? Against which standards should the aromatic properties of fullerenes be measured? ¨ Are there count rules similar to the Huckel rule? 平面型分子芳香性的判别 H 结构 H H H H H 能量 Diatropic Ring Current 反应性 核磁共振 Bexo Criteria of Fullerene’s Aromaticiy Structural criteria Energetic criteria Reactivity criteria Magnetic criteria Structural Criteria Why not: ？ Structural Criteria Crystal Structure of C60 。 [6,6]-bond length: 1.355 A 。 [5,6]-bond length: 1.467 A Liu, S. et al. Science 1991, 254, 408 Structural Criteria Structural Criteria A. Hirsch, Chem. Rev. 2001, 101, 1153 Structural Criteria Structural Criteria Bond-length alternation = Not aromatic ? Structural Criteria A. Hirsch, Chem. Rev. 2001, 101, 1153 A. Hirsch, Chem. Rev. 2001, 101, 1153